A new phosphorescent cyclometalated Iridium(III) complex for the selective detection of Silver(I) Ion

Bihai Tong; Jia Yan Qiang; Ya Qing Xu; Qunbo Mei; Qun Chen; Wa Hung Leung; Qian Feng Zhang

doi:10.1007/s10953-012-9889-1

A new phosphorescent cyclometalated Iridium(III) complex for the selective detection of Silver(I) Ion

Bihai Tong^*, Jia Yan Qiang, Ya Qing Xu, Qunbo Mei, Qun Chen, Wa Hung Leung, Qian Feng Zhang

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

4 Citations (Scopus)

Abstract

A new cyclometalated iridium(III) complex, Ir(ppz)2(dtp) (Ir1) (ppzH = 4-phenylphthalazinone, dtp = diethyl dithiophosphate), has been synthesized and characterized by single-crystal X-ray diffraction. The photoluminescence spectrum of Ir1 shows an emission maximum at 597 nm and its quantum yield is ca. 0.072. Complex Ir1 exhibits a strong and fast decrease of emission upon addition of Ag+ in aqueous media. The ratio of Ir1 responding to Ag+ was determined to be 1:1 by UV-Vis absorption and phosphorescent emission measurements. Complex Ir1 is a highly selective chemosensor for Ag+ over other transition metal ions.

Original language	English
Pages (from-to)	1600-1609
Number of pages	10
Journal	Journal of Solution Chemistry
Volume	41
Issue number	9
DOIs	https://doi.org/10.1007/s10953-012-9889-1
Publication status	Published - Oct 2012

Keywords

Cyclometalated complex
Iridium
Photoluminescence
Selective chemosensor
Silver

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10.1007/s10953-012-9889-1

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title = "A new phosphorescent cyclometalated Iridium(III) complex for the selective detection of Silver(I) Ion",

abstract = "A new cyclometalated iridium(III) complex, Ir(ppz)2(dtp) (Ir1) (ppzH = 4-phenylphthalazinone, dtp = diethyl dithiophosphate), has been synthesized and characterized by single-crystal X-ray diffraction. The photoluminescence spectrum of Ir1 shows an emission maximum at 597 nm and its quantum yield is ca. 0.072. Complex Ir1 exhibits a strong and fast decrease of emission upon addition of Ag+ in aqueous media. The ratio of Ir1 responding to Ag+ was determined to be 1:1 by UV-Vis absorption and phosphorescent emission measurements. Complex Ir1 is a highly selective chemosensor for Ag+ over other transition metal ions.",

keywords = "Cyclometalated complex, Iridium, Photoluminescence, Selective chemosensor, Silver",

author = "Bihai Tong and Qiang, \{Jia Yan\} and Xu, \{Ya Qing\} and Qunbo Mei and Qun Chen and Leung, \{Wa Hung\} and Zhang, \{Qian Feng\}",

year = "2012",

month = oct,

doi = "10.1007/s10953-012-9889-1",

language = "English",

volume = "41",

pages = "1600--1609",

journal = "Journal of Solution Chemistry",

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TY - JOUR

T1 - A new phosphorescent cyclometalated Iridium(III) complex for the selective detection of Silver(I) Ion

AU - Tong, Bihai

AU - Qiang, Jia Yan

AU - Xu, Ya Qing

AU - Mei, Qunbo

AU - Chen, Qun

AU - Leung, Wa Hung

AU - Zhang, Qian Feng

PY - 2012/10

Y1 - 2012/10

N2 - A new cyclometalated iridium(III) complex, Ir(ppz)2(dtp) (Ir1) (ppzH = 4-phenylphthalazinone, dtp = diethyl dithiophosphate), has been synthesized and characterized by single-crystal X-ray diffraction. The photoluminescence spectrum of Ir1 shows an emission maximum at 597 nm and its quantum yield is ca. 0.072. Complex Ir1 exhibits a strong and fast decrease of emission upon addition of Ag+ in aqueous media. The ratio of Ir1 responding to Ag+ was determined to be 1:1 by UV-Vis absorption and phosphorescent emission measurements. Complex Ir1 is a highly selective chemosensor for Ag+ over other transition metal ions.

AB - A new cyclometalated iridium(III) complex, Ir(ppz)2(dtp) (Ir1) (ppzH = 4-phenylphthalazinone, dtp = diethyl dithiophosphate), has been synthesized and characterized by single-crystal X-ray diffraction. The photoluminescence spectrum of Ir1 shows an emission maximum at 597 nm and its quantum yield is ca. 0.072. Complex Ir1 exhibits a strong and fast decrease of emission upon addition of Ag+ in aqueous media. The ratio of Ir1 responding to Ag+ was determined to be 1:1 by UV-Vis absorption and phosphorescent emission measurements. Complex Ir1 is a highly selective chemosensor for Ag+ over other transition metal ions.

KW - Cyclometalated complex

KW - Iridium

KW - Photoluminescence

KW - Selective chemosensor

KW - Silver

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000309355700010

UR - https://openalex.org/W2056857641

UR - https://www.scopus.com/pages/publications/84868507595

U2 - 10.1007/s10953-012-9889-1

DO - 10.1007/s10953-012-9889-1

M3 - Journal Article

SN - 0095-9782

VL - 41

SP - 1600

EP - 1609

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

IS - 9

ER -

A new phosphorescent cyclometalated Iridium(III) complex for the selective detection of Silver(I) Ion

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Keywords

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