Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh2(μ-CO){μ,μ- (CHCMe2CHCO)}(η-C5Me5)2]

Colin J. Schaverien; Michael Green; A. Guy Orpen; Ian D. Williams

doi:10.1039/C39820000912

Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh₂(μ-CO){μ,μ- (CHCMe₂CHCO)}(η-C₅Me₅)₂]

Colin J. Schaverien^*, Michael Green, A. Guy Orpen, Ian D. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

16 Citations (Scopus)

Abstract

Reaction of [Rh₂(μ-CO)₂(η-C₅Me ₅)₂] with 3,3-dimethylcyclopropene results in the cleavage of the carbon-carbon double bond, and the formation of the bridged carbene complex [Rh₂(μ-CO){μ,μ-(CHCMe₂CHCO)}(η-C ₅Me₅)₂], which was structurally identified by X-ray crystallography, and shown to undergo selective carbon-rhodium bond cleavage on treatment with CF₃CO₂H.

Original language	English
Pages (from-to)	912-914
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39820000912
Publication status	Published - 1982
Externally published	Yes

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10.1039/C39820000912

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@article{1921631ed1e640028d8dce207de094b1,

title = "Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh2(μ-CO)\{μ,μ- (CHCMe2CHCO)\}(η-C5Me5)2]",

abstract = "Reaction of [Rh2(μ-CO)2(η-C5Me 5)2] with 3,3-dimethylcyclopropene results in the cleavage of the carbon-carbon double bond, and the formation of the bridged carbene complex [Rh2(μ-CO)\{μ,μ-(CHCMe2CHCO)\}(η-C 5Me5)2], which was structurally identified by X-ray crystallography, and shown to undergo selective carbon-rhodium bond cleavage on treatment with CF3CO2H.",

author = "Schaverien, \{Colin J.\} and Michael Green and Orpen, \{A. Guy\} and Williams, \{Ian D.\}",

year = "1982",

doi = "10.1039/C39820000912",

language = "English",

pages = "912--914",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "16",

}

Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh₂(μ-CO){μ,μ- (CHCMe₂CHCO)}(η-C₅Me₅)₂]. / Schaverien, Colin J.; Green, Michael; Orpen, A. Guy et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 1982, p. 912-914.

Research output: Contribution to journal › Journal Article › peer-review

TY - JOUR

T1 - Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh2(μ-CO){μ,μ- (CHCMe2CHCO)}(η-C5Me5)2]

AU - Schaverien, Colin J.

AU - Green, Michael

AU - Orpen, A. Guy

AU - Williams, Ian D.

PY - 1982

Y1 - 1982

N2 - Reaction of [Rh2(μ-CO)2(η-C5Me 5)2] with 3,3-dimethylcyclopropene results in the cleavage of the carbon-carbon double bond, and the formation of the bridged carbene complex [Rh2(μ-CO){μ,μ-(CHCMe2CHCO)}(η-C 5Me5)2], which was structurally identified by X-ray crystallography, and shown to undergo selective carbon-rhodium bond cleavage on treatment with CF3CO2H.

AB - Reaction of [Rh2(μ-CO)2(η-C5Me 5)2] with 3,3-dimethylcyclopropene results in the cleavage of the carbon-carbon double bond, and the formation of the bridged carbene complex [Rh2(μ-CO){μ,μ-(CHCMe2CHCO)}(η-C 5Me5)2], which was structurally identified by X-ray crystallography, and shown to undergo selective carbon-rhodium bond cleavage on treatment with CF3CO2H.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:A1982PC86800015

UR - https://openalex.org/W2064099383

UR - https://www.scopus.com/pages/publications/37049099722

U2 - 10.1039/C39820000912

DO - 10.1039/C39820000912

M3 - Journal Article

SN - 0022-4936

SP - 912

EP - 914

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Alkene fragmentation at a dimetal centre; x-ray crystal structure and protonation of the bridged carbene complex [Rh₂(μ-CO){μ,μ- (CHCMe₂CHCO)}(η-C₅Me₅)₂]

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