Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

Ka Wang Chan; Wai Ming Ng; Wai Man Cheung; Chun Sing Lai; Herman H.Y. Sung; Ian D. Williams; Wa Hung Leung

doi:10.1016/j.jorganchem.2016.02.004

Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

Ka Wang Chan
, Wai Ming Ng
, Wai Man Cheung^*
, Chun Sing Lai
, Herman H.Y. Sung
, Ian D. Williams
, Wa Hung Leung

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

2 Citations (Scopus)

Abstract

Treatment of Ru(NO)Cl₃ with NaSC₆F₄H (C₆F₄HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H₂O)₂[Ru(NO)(SC₆HF₄)₂]₂(μ-SC₆HF₄)₂(μ-OH) (Na(H₂O)₂1), in which the {Na(H₂O)₂}⁺ moiety binds to the diruthenium core via the μ-hydroxo ligand and three ortho fluorine atoms of the thiolate ligands. Metathesis of Na(H₂O)₂1 with Buⁿ ₄NBr and Ph₄PCl afforded Na-free (Buⁿ ₄N)[1] and (Ph₄P)[1], respectively. Treatment of Ru(NO)Cl₃ with NaSBu^t afforded the trinuclear oxo-sulfido cluster Na(H₂O)₂[Ru(NO)(SBu^t)(μ-SBu^t)]₃(μ₃-S)(μ₃-O) (Na(H₂O)₂2) that contains a trinuclear {Ru₃(SBu^t)₃} core capped by a μ₃-oxo and a μ₃-sulfido ligand. The {Na(H₂O)₂}⁺ moiety binds to the triruthenium core via the μ₃-oxo and two terminal thiolate ligands. Metathesis of Na(H₂O)₂2 with Buⁿ ₄NBr gave (Buⁿ ₄N)[2]. Treatment of Ru(NO)Cl₃ with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)₃(tippSH) (3). The crystal structures of Na(H₂O)₂1, (Ph₄P)[1], and Na(H₂O)₂2 have been determined.

Original language	English
Pages (from-to)	151-157
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	812
DOIs	https://doi.org/10.1016/j.jorganchem.2016.02.004
Publication status	Published - 15 Jun 2016

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

Keywords

Cluster
Nitrosyl
Ruthenium
Thiolate

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10.1016/j.jorganchem.2016.02.004

Cite this

@article{ab6f2d4bfb7b42018b78cd125d4f560b,

title = "Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands",

abstract = "Treatment of Ru(NO)Cl3 with NaSC6F4H (C6F4HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H2O)2[Ru(NO)(SC6HF4)2]2(μ-SC6HF4)2(μ-OH) (Na(H2O)21), in which the \{Na(H2O)2\}+ moiety binds to the diruthenium core via the μ-hydroxo ligand and three ortho fluorine atoms of the thiolate ligands. Metathesis of Na(H2O)21 with Bun 4NBr and Ph4PCl afforded Na-free (Bun 4N)[1] and (Ph4P)[1], respectively. Treatment of Ru(NO)Cl3 with NaSBut afforded the trinuclear oxo-sulfido cluster Na(H2O)2[Ru(NO)(SBut)(μ-SBut)]3(μ3-S)(μ3-O) (Na(H2O)22) that contains a trinuclear \{Ru3(SBut)3\} core capped by a μ3-oxo and a μ3-sulfido ligand. The \{Na(H2O)2\}+ moiety binds to the triruthenium core via the μ3-oxo and two terminal thiolate ligands. Metathesis of Na(H2O)22 with Bun 4NBr gave (Bun 4N)[2]. Treatment of Ru(NO)Cl3 with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)3(tippSH) (3). The crystal structures of Na(H2O)21, (Ph4P)[1], and Na(H2O)22 have been determined.",

keywords = "Cluster, Nitrosyl, Ruthenium, Thiolate",

author = "Chan, \{Ka Wang\} and Ng, \{Wai Ming\} and Cheung, \{Wai Man\} and Lai, \{Chun Sing\} and Sung, \{Herman H.Y.\} and Williams, \{Ian D.\} and Leung, \{Wa Hung\}",

year = "2016",

month = jun,

day = "15",

doi = "10.1016/j.jorganchem.2016.02.004",

language = "English",

volume = "812",

pages = "151--157",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

AU - Chan, Ka Wang

AU - Ng, Wai Ming

AU - Cheung, Wai Man

AU - Lai, Chun Sing

AU - Sung, Herman H.Y.

AU - Williams, Ian D.

AU - Leung, Wa Hung

PY - 2016/6/15

Y1 - 2016/6/15

N2 - Treatment of Ru(NO)Cl3 with NaSC6F4H (C6F4HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H2O)2[Ru(NO)(SC6HF4)2]2(μ-SC6HF4)2(μ-OH) (Na(H2O)21), in which the {Na(H2O)2}+ moiety binds to the diruthenium core via the μ-hydroxo ligand and three ortho fluorine atoms of the thiolate ligands. Metathesis of Na(H2O)21 with Bun 4NBr and Ph4PCl afforded Na-free (Bun 4N)[1] and (Ph4P)[1], respectively. Treatment of Ru(NO)Cl3 with NaSBut afforded the trinuclear oxo-sulfido cluster Na(H2O)2[Ru(NO)(SBut)(μ-SBut)]3(μ3-S)(μ3-O) (Na(H2O)22) that contains a trinuclear {Ru3(SBut)3} core capped by a μ3-oxo and a μ3-sulfido ligand. The {Na(H2O)2}+ moiety binds to the triruthenium core via the μ3-oxo and two terminal thiolate ligands. Metathesis of Na(H2O)22 with Bun 4NBr gave (Bun 4N)[2]. Treatment of Ru(NO)Cl3 with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)3(tippSH) (3). The crystal structures of Na(H2O)21, (Ph4P)[1], and Na(H2O)22 have been determined.

AB - Treatment of Ru(NO)Cl3 with NaSC6F4H (C6F4HSH = 2,3,5,6-tetrafluorothiophenol) afforded the hydroxo-bridged dimer Na(H2O)2[Ru(NO)(SC6HF4)2]2(μ-SC6HF4)2(μ-OH) (Na(H2O)21), in which the {Na(H2O)2}+ moiety binds to the diruthenium core via the μ-hydroxo ligand and three ortho fluorine atoms of the thiolate ligands. Metathesis of Na(H2O)21 with Bun 4NBr and Ph4PCl afforded Na-free (Bun 4N)[1] and (Ph4P)[1], respectively. Treatment of Ru(NO)Cl3 with NaSBut afforded the trinuclear oxo-sulfido cluster Na(H2O)2[Ru(NO)(SBut)(μ-SBut)]3(μ3-S)(μ3-O) (Na(H2O)22) that contains a trinuclear {Ru3(SBut)3} core capped by a μ3-oxo and a μ3-sulfido ligand. The {Na(H2O)2}+ moiety binds to the triruthenium core via the μ3-oxo and two terminal thiolate ligands. Metathesis of Na(H2O)22 with Bun 4NBr gave (Bun 4N)[2]. Treatment of Ru(NO)Cl3 with NaStipp (tipp = 2,4,6-triisopropylphenyl) gave mononuclear Ru(NO)(Stipp)3(tippSH) (3). The crystal structures of Na(H2O)21, (Ph4P)[1], and Na(H2O)22 have been determined.

KW - Cluster

KW - Nitrosyl

KW - Ruthenium

KW - Thiolate

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000378192200018

UR - https://openalex.org/W2262058782

U2 - 10.1016/j.jorganchem.2016.02.004

DO - 10.1016/j.jorganchem.2016.02.004

M3 - Journal Article

SN - 0022-328X

VL - 812

SP - 151

EP - 157

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

Abstract

Bibliographical note

Keywords

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