Efficient photocatalytic reduction of aqueous Cr(VI) over flower-like SnIn4S8 microspheres under visible light illumination

Lin Wang, Xinyong Li*, Wei Teng, Qidong Zhao, Yong Shi, Renliang Yue, Yunfa Chen

*Corresponding author for this work

Research output: Contribution to journalJournal Articlepeer-review

120 Citations (Scopus)

Abstract

Photocatalytic reduction of aqueous Cr(VI) was successfully achieved on nanostructured SnIn4S8. The SnIn4S8 particles with flower-like nanostructure were synthesized via a facile solvothermal method. UV-vis diffuse reflectance spectra (DRS) indicated that the SnIn4S8 particles had strong absorption in visible region and the band gap was estimated to be from 2.27 to 2.35eV. The photocatalytic reduction of aqueous Cr(VI) by flower-like SnIn4S8 was evaluated under visible light (λ>400nm) irradiation. The polyvinyl pyrrolidone (PVP) assisted SnIn4S8 sample exhibits excellent removal efficiency of Cr(VI) (∼97%) and good photocatalytic stability. The predominant photocatalytic activity is due to its large surface area, strong absorption in visible-light region and excellent charge separation characteristics.

Original languageEnglish
Pages (from-to)681-688
Number of pages8
JournalJournal of Hazardous Materials
Volume244-245
DOIs
Publication statusPublished - 5 Jan 2013
Externally publishedYes

Keywords

  • Cr(VI) reduction
  • Flower-like
  • Photocatalytic
  • SnInS
  • Surfactants

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