Experimental and theoretical studies of the propargyl-allenylindium system

Weishi Miao; Lung Wa Chung; Yun Dong Wu; Tak Hang Chan

doi:10.1021/ja049241n

Experimental and theoretical studies of the propargyl-allenylindium system

Weishi Miao, Lung Wa Chung, Yun Dong Wu, Tak Hang Chan^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

58 Citations (Scopus)

Abstract

The transient organoindium intermediates formed in the reaction of propargyl bromide with indium in aqueous media and tetrahydrofuran were investigated by NMR spectroscopy and found to be allenylindium(I) and allenylindium(III) dibromide. The influence of solvent and methyl substitution on the propargyl-allenylindium system was also studied. The experimental observations were supported by theoretical calculations using the B3LYP/6-311+G* method.

Original language	English
Pages (from-to)	13326-13334
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	126
Issue number	41
DOIs	https://doi.org/10.1021/ja049241n
Publication status	Published - 20 Oct 2004

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title = "Experimental and theoretical studies of the propargyl-allenylindium system",

abstract = "The transient organoindium intermediates formed in the reaction of propargyl bromide with indium in aqueous media and tetrahydrofuran were investigated by NMR spectroscopy and found to be allenylindium(I) and allenylindium(III) dibromide. The influence of solvent and methyl substitution on the propargyl-allenylindium system was also studied. The experimental observations were supported by theoretical calculations using the B3LYP/6-311+G* method.",

author = "Weishi Miao and Chung, \{Lung Wa\} and Wu, \{Yun Dong\} and Chan, \{Tak Hang\}",

year = "2004",

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T1 - Experimental and theoretical studies of the propargyl-allenylindium system

AU - Miao, Weishi

AU - Chung, Lung Wa

AU - Wu, Yun Dong

AU - Chan, Tak Hang

PY - 2004/10/20

Y1 - 2004/10/20

N2 - The transient organoindium intermediates formed in the reaction of propargyl bromide with indium in aqueous media and tetrahydrofuran were investigated by NMR spectroscopy and found to be allenylindium(I) and allenylindium(III) dibromide. The influence of solvent and methyl substitution on the propargyl-allenylindium system was also studied. The experimental observations were supported by theoretical calculations using the B3LYP/6-311+G* method.

AB - The transient organoindium intermediates formed in the reaction of propargyl bromide with indium in aqueous media and tetrahydrofuran were investigated by NMR spectroscopy and found to be allenylindium(I) and allenylindium(III) dibromide. The influence of solvent and methyl substitution on the propargyl-allenylindium system was also studied. The experimental observations were supported by theoretical calculations using the B3LYP/6-311+G* method.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000224500000050

UR - https://openalex.org/W2003205652

UR - https://www.scopus.com/pages/publications/6044221426

U2 - 10.1021/ja049241n

DO - 10.1021/ja049241n

M3 - Journal Article

SN - 0002-7863

VL - 126

SP - 13326

EP - 13334

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 41

ER -

Experimental and theoretical studies of the propargyl-allenylindium system

Abstract

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