Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone

Oksana Pietraszkiewicz; Suraj Mal; Marek Pietraszkiewicz; Michał MacIejczyk; Igor Czerski; Teresa Borowiak; Grzegorz Dutkiewicz; Oksana Drobchak; Lieven Penninck; Jeroen Beeckman; Kristiaan Neyts

doi:10.1016/j.jphotochem.2012.10.003

Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone

Oksana Pietraszkiewicz, Suraj Mal, Marek Pietraszkiewicz^*, Michał MacIejczyk, Igor Czerski, Teresa Borowiak, Grzegorz Dutkiewicz, Oksana Drobchak, Lieven Penninck, Jeroen Beeckman, Kristiaan Neyts

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

20 Citations (Scopus)

Abstract

The new triphenylene 1,3-diketone (1-triphenylen-2-yl-3- trifluoroacetylacetone (TphTA)) and its europium complexes were synthesized. The preliminary data on photophysical properties of Eu(TphTA)₃(H ₂O)(C₂H₅OH) (1), Eu(TphTA)₃(TOPO) (H₂O) (2), Eu(TphTA)₃(TOPO)₂ (3) and Eu(TphTA)₂NO₃(TOPO)₂ (4) are reported. Addition of a tri-n-octylphosphine oxide (TOPO) co-ligand to the europium diketonate complex removes water molecules from the coordination sphere, that leads to a significant increase of the photoluminescence quantum yield. The behavior of complexes 3 and 4 in nematic liquid crystal was investigated.

Original language	English
Pages (from-to)	85-91
Number of pages	7
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	250
DOIs	https://doi.org/10.1016/j.jphotochem.2012.10.003
Publication status	Published - 15 Dec 2012
Externally published	Yes

Keywords

1,3-Diketonate
Europium complexes
Liquid crystals
Luminescence
Quantum yield
Triphenylene

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10.1016/j.jphotochem.2012.10.003

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Pietraszkiewicz, O., Mal, S., Pietraszkiewicz, M., MacIejczyk, M., Czerski, I., Borowiak, T., Dutkiewicz, G., Drobchak, O., Penninck, L., Beeckman, J., & Neyts, K. (2012). Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone. Journal of Photochemistry and Photobiology A: Chemistry, 250, 85-91. https://doi.org/10.1016/j.jphotochem.2012.10.003

@article{4485c0c551554963a2b9c7e38d9213f3,

title = "Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone",

abstract = "The new triphenylene 1,3-diketone (1-triphenylen-2-yl-3- trifluoroacetylacetone (TphTA)) and its europium complexes were synthesized. The preliminary data on photophysical properties of Eu(TphTA)3(H 2O)(C2H5OH) (1), Eu(TphTA)3(TOPO) (H2O) (2), Eu(TphTA)3(TOPO)2 (3) and Eu(TphTA)2NO3(TOPO)2 (4) are reported. Addition of a tri-n-octylphosphine oxide (TOPO) co-ligand to the europium diketonate complex removes water molecules from the coordination sphere, that leads to a significant increase of the photoluminescence quantum yield. The behavior of complexes 3 and 4 in nematic liquid crystal was investigated.",

keywords = "1,3-Diketonate, Europium complexes, Liquid crystals, Luminescence, Quantum yield, Triphenylene",

author = "Oksana Pietraszkiewicz and Suraj Mal and Marek Pietraszkiewicz and Micha{\l} MacIejczyk and Igor Czerski and Teresa Borowiak and Grzegorz Dutkiewicz and Oksana Drobchak and Lieven Penninck and Jeroen Beeckman and Kristiaan Neyts",

year = "2012",

month = dec,

day = "15",

doi = "10.1016/j.jphotochem.2012.10.003",

language = "English",

volume = "250",

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journal = "Journal of Photochemistry and Photobiology A: Chemistry",

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Pietraszkiewicz, O, Mal, S, Pietraszkiewicz, M, MacIejczyk, M, Czerski, I, Borowiak, T, Dutkiewicz, G, Drobchak, O, Penninck, L, Beeckman, J & Neyts, K 2012, 'Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone', Journal of Photochemistry and Photobiology A: Chemistry, vol. 250, pp. 85-91. https://doi.org/10.1016/j.jphotochem.2012.10.003

TY - JOUR

T1 - Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone

AU - Pietraszkiewicz, Oksana

AU - Mal, Suraj

AU - Pietraszkiewicz, Marek

AU - MacIejczyk, Michał

AU - Czerski, Igor

AU - Borowiak, Teresa

AU - Dutkiewicz, Grzegorz

AU - Drobchak, Oksana

AU - Penninck, Lieven

AU - Beeckman, Jeroen

AU - Neyts, Kristiaan

PY - 2012/12/15

Y1 - 2012/12/15

N2 - The new triphenylene 1,3-diketone (1-triphenylen-2-yl-3- trifluoroacetylacetone (TphTA)) and its europium complexes were synthesized. The preliminary data on photophysical properties of Eu(TphTA)3(H 2O)(C2H5OH) (1), Eu(TphTA)3(TOPO) (H2O) (2), Eu(TphTA)3(TOPO)2 (3) and Eu(TphTA)2NO3(TOPO)2 (4) are reported. Addition of a tri-n-octylphosphine oxide (TOPO) co-ligand to the europium diketonate complex removes water molecules from the coordination sphere, that leads to a significant increase of the photoluminescence quantum yield. The behavior of complexes 3 and 4 in nematic liquid crystal was investigated.

AB - The new triphenylene 1,3-diketone (1-triphenylen-2-yl-3- trifluoroacetylacetone (TphTA)) and its europium complexes were synthesized. The preliminary data on photophysical properties of Eu(TphTA)3(H 2O)(C2H5OH) (1), Eu(TphTA)3(TOPO) (H2O) (2), Eu(TphTA)3(TOPO)2 (3) and Eu(TphTA)2NO3(TOPO)2 (4) are reported. Addition of a tri-n-octylphosphine oxide (TOPO) co-ligand to the europium diketonate complex removes water molecules from the coordination sphere, that leads to a significant increase of the photoluminescence quantum yield. The behavior of complexes 3 and 4 in nematic liquid crystal was investigated.

KW - 1,3-Diketonate

KW - Europium complexes

KW - Liquid crystals

KW - Luminescence

KW - Quantum yield

KW - Triphenylene

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000312524700012

UR - https://openalex.org/W1978997781

UR - https://www.scopus.com/pages/publications/84868236769

U2 - 10.1016/j.jphotochem.2012.10.003

DO - 10.1016/j.jphotochem.2012.10.003

M3 - Journal Article

SN - 1010-6030

VL - 250

SP - 85

EP - 91

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

ER -

Highly photoluminescent Eu(III) complexes of the new 1-triphenylen-2-yl-3- trifluoroacetylacetone

Abstract

Keywords

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