Hydrolysis and coordination behavior of ferrocenyl-phosphonodithiolate: Synthesis and structure of Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 [Fc = Fe(η5-C5H4)(η5-C5H5)]

Shu Lei Liu; Xi Ying Wang; Taike Duan; Wa Hung Leung; Qian Feng Zhang

doi:10.1016/j.molstruc.2009.11.014

Hydrolysis and coordination behavior of ferrocenyl-phosphonodithiolate: Synthesis and structure of Cu₄[FcP(OCH₃)(μ-S)(μ₃-S)]₄ [Fc = Fe(η⁵-C₅H₄)(η⁵-C₅H₅)]

Shu Lei Liu, Xi Ying Wang, Taike Duan, Wa Hung Leung, Qian Feng Zhang^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

16 Citations (Scopus)

Abstract

Treatment of the dimeric [FcP(S)(μ-S)]₂ [Fc = Fe(η⁵-C₅H₄)(η⁵-C₅H₅)] with the organic base Et₃N in methylene chloride solution resulted in the isolation of a multi-component compound [Et₃NH]₂[(FcPO₂S)₂CH₂][FcPS(OH)₂]₂·CH₂Cl₂ (1·CH₂Cl₂). The formation of the [(FcPO₂S)₂CH₂]^2- anion was due to the dechlorination of methylene chloride, it consists of two [FcPO₂S]^2- units bridging by a methylene group. Reaction of Na[FcP(OCH₃)S₂] with equal equivalent of [Cu(MeCN)₄][ClO₄] in methanol afforded a sole tetranuclear copper(I) complex Cu₄[FcP(OCH₃)(μ-S)(μ₃-S)]₄ (2). The neutral complex 2 consists of a crystallographically centrosymmetric tetramer containing four CuS₃ arrays each of which has one μ-sulfur and two μ₃-sulfur bridges.

Original language	English
Pages (from-to)	78-81
Number of pages	4
Journal	Journal of Molecular Structure
Volume	964
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2009.11.014
Publication status	Published - 14 Feb 2010

Keywords

Copper
Crystal structure
Ferrocene
Phosphonodithioate
Synthesis

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@article{8a73c656477441929f976a15c82dbc51,

title = "Hydrolysis and coordination behavior of ferrocenyl-phosphonodithiolate: Synthesis and structure of Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 [Fc = Fe(η5-C5H4)(η5-C5H5)]",

abstract = "Treatment of the dimeric [FcP(S)(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C5H5)] with the organic base Et3N in methylene chloride solution resulted in the isolation of a multi-component compound [Et3NH]2[(FcPO2S)2CH2][FcPS(OH)2]2·CH2Cl2 (1·CH2Cl2). The formation of the [(FcPO2S)2CH2]2- anion was due to the dechlorination of methylene chloride, it consists of two [FcPO2S]2- units bridging by a methylene group. Reaction of Na[FcP(OCH3)S2] with equal equivalent of [Cu(MeCN)4][ClO4] in methanol afforded a sole tetranuclear copper(I) complex Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 (2). The neutral complex 2 consists of a crystallographically centrosymmetric tetramer containing four CuS3 arrays each of which has one μ-sulfur and two μ3-sulfur bridges.",

keywords = "Copper, Crystal structure, Ferrocene, Phosphonodithioate, Synthesis",

author = "Liu, \{Shu Lei\} and Wang, \{Xi Ying\} and Taike Duan and Leung, \{Wa Hung\} and Zhang, \{Qian Feng\}",

year = "2010",

month = feb,

day = "14",

doi = "10.1016/j.molstruc.2009.11.014",

language = "English",

volume = "964",

pages = "78--81",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Hydrolysis and coordination behavior of ferrocenyl-phosphonodithiolate

T2 - Synthesis and structure of Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 [Fc = Fe(η5-C5H4)(η5-C5H5)]

AU - Liu, Shu Lei

AU - Wang, Xi Ying

AU - Duan, Taike

AU - Leung, Wa Hung

AU - Zhang, Qian Feng

PY - 2010/2/14

Y1 - 2010/2/14

N2 - Treatment of the dimeric [FcP(S)(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C5H5)] with the organic base Et3N in methylene chloride solution resulted in the isolation of a multi-component compound [Et3NH]2[(FcPO2S)2CH2][FcPS(OH)2]2·CH2Cl2 (1·CH2Cl2). The formation of the [(FcPO2S)2CH2]2- anion was due to the dechlorination of methylene chloride, it consists of two [FcPO2S]2- units bridging by a methylene group. Reaction of Na[FcP(OCH3)S2] with equal equivalent of [Cu(MeCN)4][ClO4] in methanol afforded a sole tetranuclear copper(I) complex Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 (2). The neutral complex 2 consists of a crystallographically centrosymmetric tetramer containing four CuS3 arrays each of which has one μ-sulfur and two μ3-sulfur bridges.

AB - Treatment of the dimeric [FcP(S)(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C5H5)] with the organic base Et3N in methylene chloride solution resulted in the isolation of a multi-component compound [Et3NH]2[(FcPO2S)2CH2][FcPS(OH)2]2·CH2Cl2 (1·CH2Cl2). The formation of the [(FcPO2S)2CH2]2- anion was due to the dechlorination of methylene chloride, it consists of two [FcPO2S]2- units bridging by a methylene group. Reaction of Na[FcP(OCH3)S2] with equal equivalent of [Cu(MeCN)4][ClO4] in methanol afforded a sole tetranuclear copper(I) complex Cu4[FcP(OCH3)(μ-S)(μ3-S)]4 (2). The neutral complex 2 consists of a crystallographically centrosymmetric tetramer containing four CuS3 arrays each of which has one μ-sulfur and two μ3-sulfur bridges.

KW - Copper

KW - Crystal structure

KW - Ferrocene

KW - Phosphonodithioate

KW - Synthesis

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000274673100014

UR - https://openalex.org/W2088255980

UR - https://www.scopus.com/pages/publications/73749088361

U2 - 10.1016/j.molstruc.2009.11.014

DO - 10.1016/j.molstruc.2009.11.014

M3 - Journal Article

SN - 0022-2860

VL - 964

SP - 78

EP - 81

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Hydrolysis and coordination behavior of ferrocenyl-phosphonodithiolate: Synthesis and structure of Cu₄[FcP(OCH₃)(μ-S)(μ₃-S)]₄ [Fc = Fe(η⁵-C₅H₄)(η⁵-C₅H₅)]

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