Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

J. F. Wang; M. A. Hubbard; Y. Jin; J. T. Lin; T. J. Marks; W. P. Lin; G. K. Wong

doi:10.1117/12.165303

Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

J. F. Wang, M. A. Hubbard, Y. Jin, J. T. Lin, T. J. Marks, W. P. Lin, G. K. Wong

Research output: Contribution to journal › Conference article published in journal › peer-review

4 Citations (Scopus)

Abstract

Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve T_g values approaching + 240°C and exceptional SHG temporal stability.

Original language	English
Pages (from-to)	62-68
Number of pages	7
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	2025
DOIs	https://doi.org/10.1117/12.165303
Publication status	Published - 16 Dec 1993
Externally published	Yes
Event	Nonlinear Optical Properties of Organic Materials VI 1993 - San Diego, United States Duration: 11 Jul 1993 → 16 Jul 1993

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© 1993 SPIE. All rights reserved.

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Wang, J. F., Hubbard, M. A., Jin, Y., Lin, J. T., Marks, T. J., Lin, W. P., & Wong, G. K. (1993). Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems. Proceedings of SPIE - The International Society for Optical Engineering, 2025, 62-68. https://doi.org/10.1117/12.165303

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title = "Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems",

abstract = "Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.",

author = "Wang, \{J. F.\} and Hubbard, \{M. A.\} and Y. Jin and Lin, \{J. T.\} and Marks, \{T. J.\} and Lin, \{W. P.\} and Wong, \{G. K.\}",

year = "1993",

month = dec,

day = "16",

doi = "10.1117/12.165303",

language = "English",

volume = "2025",

pages = "62--68",

journal = "Proceedings of SPIE - The International Society for Optical Engineering",

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Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems. / Wang, J. F.; Hubbard, M. A.; Jin, Y. et al.
In: Proceedings of SPIE - The International Society for Optical Engineering, Vol. 2025, 16.12.1993, p. 62-68.

Research output: Contribution to journal › Conference article published in journal › peer-review

TY - JOUR

T1 - Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

AU - Wang, J. F.

AU - Hubbard, M. A.

AU - Jin, Y.

AU - Lin, J. T.

AU - Marks, T. J.

AU - Lin, W. P.

AU - Wong, G. K.

PY - 1993/12/16

Y1 - 1993/12/16

N2 - Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.

AB - Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.

UR - https://www.scopus.com/pages/publications/85076210384

U2 - 10.1117/12.165303

DO - 10.1117/12.165303

M3 - Conference article published in journal

AN - SCOPUS:85076210384

SN - 0277-786X

VL - 2025

SP - 62

EP - 68

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

T2 - Nonlinear Optical Properties of Organic Materials VI 1993

Y2 - 11 July 1993 through 16 July 1993

ER -

Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

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