Mixed reforming of heptane to syngas in the Ba0.5Sr 0.5Co0.8Fe0.2O3 membrane reactor

Wenliang Zhu; Wei Han; Guoxing Xiong; Weishen Yang

doi:10.1016/j.cattod.2005.03.072

Mixed reforming of heptane to syngas in the Ba_0.5Sr _0.5Co_0.8Fe_0.2O₃ membrane reactor

Wenliang Zhu, Wei Han, Guoxing Xiong^*, Weishen Yang

^*Corresponding author for this work

Research output: Contribution to journal › Conference article published in journal › peer-review

29 Citations (Scopus)

Abstract

Fuel cells are recognized as the most promising new power generation technology, but hydrogen supply is still a problem. In our previous work, we have developed a LiLaNiO/γ-Al₂O₃ catalyst, which is excellent not only for partial oxidation of hydrocarbons, but also for steam reforming and autothermal reforming. However, the reaction needs pure oxygen or air as oxidant. We have developed a dense oxygen permeable membrane Ba _0.5Sr_0.5Co_0.8Fe_0.2O₃ which has an oxygen permeation flux around 11.5 ml/cm² min at reaction conditions. Therefore, this work is to combine the oxygen permeable membrane with the catalyst LiLaNiO/γ-Al₂O₃ in a membrane reactor for hydrogen production by mixed reforming of heptane. Under optimized reaction conditions, a heptane conversion of 100%, a CO selectivity of 91-93% and a H₂ selectivity of 95-97% have been achieved.

Original language	English
Pages (from-to)	149-153
Number of pages	5
Journal	Catalysis Today
Volume	104
Issue number	2-4
DOIs	https://doi.org/10.1016/j.cattod.2005.03.072
Publication status	Published - 30 Jun 2005
Externally published	Yes
Event	Catalysis in Membrane Reactors - Duration: 6 Jul 2004 → 9 Jul 2004

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Heptane
Hydrogen production
Membrane reactor
Mixed reforming
Syngas

Access to Document

10.1016/j.cattod.2005.03.072

Cite this

@article{fb9619a84c1e46a1aa92014e30a8d62d,

title = "Mixed reforming of heptane to syngas in the Ba0.5Sr 0.5Co0.8Fe0.2O3 membrane reactor",

abstract = "Fuel cells are recognized as the most promising new power generation technology, but hydrogen supply is still a problem. In our previous work, we have developed a LiLaNiO/γ-Al2O3 catalyst, which is excellent not only for partial oxidation of hydrocarbons, but also for steam reforming and autothermal reforming. However, the reaction needs pure oxygen or air as oxidant. We have developed a dense oxygen permeable membrane Ba 0.5Sr0.5Co0.8Fe0.2O3 which has an oxygen permeation flux around 11.5 ml/cm2 min at reaction conditions. Therefore, this work is to combine the oxygen permeable membrane with the catalyst LiLaNiO/γ-Al2O3 in a membrane reactor for hydrogen production by mixed reforming of heptane. Under optimized reaction conditions, a heptane conversion of 100\%, a CO selectivity of 91-93\% and a H2 selectivity of 95-97\% have been achieved.",

keywords = "Heptane, Hydrogen production, Membrane reactor, Mixed reforming, Syngas",

author = "Wenliang Zhu and Wei Han and Guoxing Xiong and Weishen Yang",

year = "2005",

month = jun,

day = "30",

doi = "10.1016/j.cattod.2005.03.072",

language = "English",

volume = "104",

pages = "149--153",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier B.V.",

number = "2-4",

note = "Catalysis in Membrane Reactors ; Conference date: 06-07-2004 Through 09-07-2004",

}

TY - JOUR

T1 - Mixed reforming of heptane to syngas in the Ba0.5Sr 0.5Co0.8Fe0.2O3 membrane reactor

AU - Zhu, Wenliang

AU - Han, Wei

AU - Xiong, Guoxing

AU - Yang, Weishen

PY - 2005/6/30

Y1 - 2005/6/30

N2 - Fuel cells are recognized as the most promising new power generation technology, but hydrogen supply is still a problem. In our previous work, we have developed a LiLaNiO/γ-Al2O3 catalyst, which is excellent not only for partial oxidation of hydrocarbons, but also for steam reforming and autothermal reforming. However, the reaction needs pure oxygen or air as oxidant. We have developed a dense oxygen permeable membrane Ba 0.5Sr0.5Co0.8Fe0.2O3 which has an oxygen permeation flux around 11.5 ml/cm2 min at reaction conditions. Therefore, this work is to combine the oxygen permeable membrane with the catalyst LiLaNiO/γ-Al2O3 in a membrane reactor for hydrogen production by mixed reforming of heptane. Under optimized reaction conditions, a heptane conversion of 100%, a CO selectivity of 91-93% and a H2 selectivity of 95-97% have been achieved.

AB - Fuel cells are recognized as the most promising new power generation technology, but hydrogen supply is still a problem. In our previous work, we have developed a LiLaNiO/γ-Al2O3 catalyst, which is excellent not only for partial oxidation of hydrocarbons, but also for steam reforming and autothermal reforming. However, the reaction needs pure oxygen or air as oxidant. We have developed a dense oxygen permeable membrane Ba 0.5Sr0.5Co0.8Fe0.2O3 which has an oxygen permeation flux around 11.5 ml/cm2 min at reaction conditions. Therefore, this work is to combine the oxygen permeable membrane with the catalyst LiLaNiO/γ-Al2O3 in a membrane reactor for hydrogen production by mixed reforming of heptane. Under optimized reaction conditions, a heptane conversion of 100%, a CO selectivity of 91-93% and a H2 selectivity of 95-97% have been achieved.

KW - Heptane

KW - Hydrogen production

KW - Membrane reactor

KW - Mixed reforming

KW - Syngas

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000230204100008

UR - https://openalex.org/W2123855773

UR - https://www.scopus.com/pages/publications/31344459371

U2 - 10.1016/j.cattod.2005.03.072

DO - 10.1016/j.cattod.2005.03.072

M3 - Conference article published in journal

SN - 0920-5861

VL - 104

SP - 149

EP - 153

JO - Catalysis Today

JF - Catalysis Today

IS - 2-4

T2 - Catalysis in Membrane Reactors

Y2 - 6 July 2004 through 9 July 2004

ER -