Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Shaobin Miao; Qian Feng Zhang; Wa Hung Leung

doi:10.3184/0308234043431771

Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Shaobin Miao, Qian Feng Zhang^*, Wa Hung Leung

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

1 Citation (Scopus)

Abstract

Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

Original language	English
Pages (from-to)	714-715
Number of pages	2
Journal	Journal of Chemical Research
Issue number	10
DOIs	https://doi.org/10.3184/0308234043431771
Publication status	Published - Oct 2004

Keywords

Crystal structures
Enynes
Ferrocenes
Optical nonlinearity
Polyynes

Access to Document

10.3184/0308234043431771

Cite this

@article{50225c0e44f44609b4f74abaf1f8a2f6,

title = "Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne",

abstract = "Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.",

keywords = "Crystal structures, Enynes, Ferrocenes, Optical nonlinearity, Polyynes",

author = "Shaobin Miao and Zhang, \{Qian Feng\} and Leung, \{Wa Hung\}",

year = "2004",

month = oct,

doi = "10.3184/0308234043431771",

language = "English",

pages = "714--715",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Scientific Reviews 2000 Ltd.",

number = "10",

}

TY - JOUR

T1 - Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

AU - Miao, Shaobin

AU - Zhang, Qian Feng

AU - Leung, Wa Hung

PY - 2004/10

Y1 - 2004/10

N2 - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

AB - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

KW - Crystal structures

KW - Enynes

KW - Ferrocenes

KW - Optical nonlinearity

KW - Polyynes

UR - https://openalex.org/W2033356266

UR - https://www.scopus.com/pages/publications/10944246147

U2 - 10.3184/0308234043431771

DO - 10.3184/0308234043431771

M3 - Journal Article

SN - 0308-2342

SP - 714

EP - 715

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 10

ER -

Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this