Abstract
We use a new variational method recently proposed for treating the ground state of quantum crystals to calculate properties of solid He4. Key improvements over previous variational calculations include avoiding a low-order cluster expansion in determining the density distribution function, and using a quite general and correctly symmetrized single-particle wave function. The variational calculation, which is unrestricted, predicts the correct solidification density within 10%, but the binding energy is about 0.5°K too low possibly because of a superposition approximation. The pressure is in good agreement with experiment. The density distribution function has a Lindemann ratio of 0.24 in accordance with expectations, but the corresponding single-particle wave function is much more spread out. The important implications this result has for the possible existence of Bose-Einstein condensation in solid He4, and also for the size of the exchange integral in solid He3, are briefly discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 3790-3798 |
| Number of pages | 9 |
| Journal | Physical Review B |
| Volume | 13 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1976 |
| Externally published | Yes |