Abstract
Highly oriented and uniform-sized Cu2S nanowire arrays grown on copper substrates have been studied by high-resolution transmission electron microscopy. Cu2S nanowires consist of single crystalline cores of Cu2S and polycrystalline Cu2O shells. Most Cu2S nanowires have a similar crystalline orientation and their growth directions were [001]Cu(2)S as determined by electron diffraction and HRTEM. The orientation relationship between Cu2S crystalline core and Cu2O crystals in the shells was determined to be (100)Cu(2)S∥(110)Cu(2)O and [010]Cu(2)S∥〈111〉Cu(2) O. The nucleation and growth process of Cu2S nanowires were interpreted by oxide-assisted growth mechanism.
| Original language | English |
|---|---|
| Pages (from-to) | 226-232 |
| Number of pages | 7 |
| Journal | Journal of Crystal Growth |
| Volume | 233 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Nov 2001 |
Keywords
- A1. crystal structure
- A1. growth models
- B1. nanomaterials