Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines

Linglong Ding; Yi Hui Deng; Tian Yu Sun; Dawei Wang; Yun Dong Wu; Xiao Feng Xia

doi:10.1039/d1qo00581b

Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines

Linglong Ding, Yi Hui Deng, Tian Yu Sun, Dawei Wang, Yun Dong Wu, Xiao Feng Xia^*

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

17 Citations (Scopus)

Abstract

With control by functional groups, catalytic divergent cycloisomerization of 1,6-enynes is achieved for the synthesis of pyrrole, cyclopentene, and tetra-hydropyridine derivatives using the combination of a Pd(0) catalyst with glucose. Detailed DFT calculations have provided evidence for the different pathways of selective cyclization/isomerization.

Original language	English
Pages (from-to)	4785-4790
Number of pages	6
Journal	Organic Chemistry Frontiers
Volume	8
Issue number	17
DOIs	https://doi.org/10.1039/d1qo00581b
Publication status	Published - 7 Sept 2021
Externally published	Yes

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title = "Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines",

abstract = "With control by functional groups, catalytic divergent cycloisomerization of 1,6-enynes is achieved for the synthesis of pyrrole, cyclopentene, and tetra-hydropyridine derivatives using the combination of a Pd(0) catalyst with glucose. Detailed DFT calculations have provided evidence for the different pathways of selective cyclization/isomerization.",

author = "Linglong Ding and Deng, \{Yi Hui\} and Sun, \{Tian Yu\} and Dawei Wang and Wu, \{Yun Dong\} and Xia, \{Xiao Feng\}",

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doi = "10.1039/d1qo00581b",

language = "English",

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T1 - Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines

AU - Ding, Linglong

AU - Deng, Yi Hui

AU - Sun, Tian Yu

AU - Wang, Dawei

AU - Wu, Yun Dong

AU - Xia, Xiao Feng

PY - 2021/9/7

Y1 - 2021/9/7

N2 - With control by functional groups, catalytic divergent cycloisomerization of 1,6-enynes is achieved for the synthesis of pyrrole, cyclopentene, and tetra-hydropyridine derivatives using the combination of a Pd(0) catalyst with glucose. Detailed DFT calculations have provided evidence for the different pathways of selective cyclization/isomerization.

AB - With control by functional groups, catalytic divergent cycloisomerization of 1,6-enynes is achieved for the synthesis of pyrrole, cyclopentene, and tetra-hydropyridine derivatives using the combination of a Pd(0) catalyst with glucose. Detailed DFT calculations have provided evidence for the different pathways of selective cyclization/isomerization.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000667337200001

UR - https://www.scopus.com/pages/publications/85113805941

U2 - 10.1039/d1qo00581b

DO - 10.1039/d1qo00581b

M3 - Journal Article

SN - 2052-4110

VL - 8

SP - 4785

EP - 4790

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 17

ER -

Palladium-catalyzed divergent cycloisomerization of 1,6-enynes controlled by functional groups for the synthesis of pyrroles, cyclopentenes, and tetrahydropyridines

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