Palladium-Catalyzed Regioselective Intramolecular Coupling of o -Carborane with Aromatics via Direct Cage B-H Activation

Yangjian Quan, Zuowei Xie*

*Corresponding author for this work

Research output: Contribution to journalJournal Articlepeer-review

87 Citations (Scopus)

Abstract

Palladium-catalyzed intramolecular coupling of o-carborane with aromatics via direct cage B-H bond activation has been achieved, leading to the synthesis of a series of o-carborane-functionalized aromatics in high yields with excellent regioselectivity. In addition, the site selectivity can also be tuned by the substituents on cage carbon atom.

Original languageEnglish
Pages (from-to)3502-3505
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number10
DOIs
Publication statusPublished - 18 Mar 2015
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

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