Regioselective ring opening of disubstituted epoxides mediated by imido(halo)metal complexes

Wa Hung Leung; Terry K.T. Wong; Jeff C.H. Tran; Lam Lung Yeung

Regioselective ring opening of disubstituted epoxides mediated by imido(halo)metal complexes

Wa Hung Leung^*
, Terry K.T. Wong
, Jeff C.H. Tran
, Lam Lung Yeung

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

13 Citations (Scopus)

Abstract

Imido(halo)metal complexes [Cr(N-t-Bu)X₃(dme)] (X = Cl, Br; dme = 1,2- dimethoxyethane) or [V(Ntol)Cl₃] (tol = ptolyl) react stoichiometrically and catalytically with epoxy benzyl ethers to give halohydrins in high regioselectivity.

Original language	English
Pages (from-to)	677-679
Number of pages	3
Journal	Synlett
Issue number	5
Publication status	Published - 2000

Keywords

Chlorohydrins, imido-metal complexes
Epoxides
Regioselective
Ring opening

Cite this

@article{95523e9dd9b34be3be270923615adc12,

title = "Regioselective ring opening of disubstituted epoxides mediated by imido(halo)metal complexes",

abstract = "Imido(halo)metal complexes [Cr(N-t-Bu)X3(dme)] (X = Cl, Br; dme = 1,2- dimethoxyethane) or [V(Ntol)Cl3] (tol = ptolyl) react stoichiometrically and catalytically with epoxy benzyl ethers to give halohydrins in high regioselectivity.",

keywords = "Chlorohydrins, imido-metal complexes, Epoxides, Regioselective, Ring opening",

author = "Leung, \{Wa Hung\} and Wong, \{Terry K.T.\} and Tran, \{Jeff C.H.\} and Yeung, \{Lam Lung\}",

year = "2000",

language = "English",

pages = "677--679",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "5",

}

TY - JOUR

T1 - Regioselective ring opening of disubstituted epoxides mediated by imido(halo)metal complexes

AU - Leung, Wa Hung

AU - Wong, Terry K.T.

AU - Tran, Jeff C.H.

AU - Yeung, Lam Lung

PY - 2000

Y1 - 2000

N2 - Imido(halo)metal complexes [Cr(N-t-Bu)X3(dme)] (X = Cl, Br; dme = 1,2- dimethoxyethane) or [V(Ntol)Cl3] (tol = ptolyl) react stoichiometrically and catalytically with epoxy benzyl ethers to give halohydrins in high regioselectivity.

AB - Imido(halo)metal complexes [Cr(N-t-Bu)X3(dme)] (X = Cl, Br; dme = 1,2- dimethoxyethane) or [V(Ntol)Cl3] (tol = ptolyl) react stoichiometrically and catalytically with epoxy benzyl ethers to give halohydrins in high regioselectivity.

KW - Chlorohydrins, imido-metal complexes

KW - Epoxides

KW - Regioselective

KW - Ring opening

UR - https://www.scopus.com/pages/publications/0034115101

M3 - Journal Article

AN - SCOPUS:0034115101

SN - 0936-5214

SP - 677

EP - 679

JO - Synlett

JF - Synlett

IS - 5

ER -

Regioselective ring opening of disubstituted epoxides mediated by imido(halo)metal complexes

Abstract

Keywords

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