Resonance Raman Study of Tetrakis(p-sulfonatophenyl) porphyrin Diacid (H2+4TSPP) Molecular Aggregates

Dong Ming Chen; Xiao Yuan Li; Nai Teng Yu; Ying Hui Zhang; Tian Jing He; Fan Zhen Liu

Resonance Raman Study of Tetrakis(p-sulfonatophenyl) porphyrin Diacid (H²⁺₄TSPP) Molecular Aggregates

Dong Ming Chen^*, Xiao Yuan Li, Nai Teng Yu, Ying Hui Zhang, Tian Jing He, Fan Zhen Liu

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

Abstract

Polarized resonance Raman spectra of J-aggregated tetrakis(p-sulfonatophenyl) porphyrin diacid (H²⁺₄TSPP) were reported. In addition, resonance Raman spectra of molecular state H²⁺₄TSPP and the free base H₂TSPP were also recorded for comparison. The observed Raman bands of the aggregates were assigned based on their isotopic shifts upon deuteration. The low-frequency bands at 81, 119 and 141 cm^-1 were assigned to intermolecular lattice modes. The structure alteration of H²⁺₄TSPP induced by the aggregation was evaluated by comparing the resonance Raman spectra of the aggregated H²⁺₄TSPP with those of the molecular state H²⁺₄TSPP. It was deduced that H²⁺₄TSPP in the aggregates is arranged in a face-to-face manner.

Original language	English
Pages (from-to)	1101
Number of pages	1
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	20
Issue number	7
Publication status	Published - 10 Jul 1999

Keywords

Molecular aggregates
Porphyrins
Resonance raman

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https://hdl.handle.net/1783.1/24977

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@article{3c138667c9254789ac07532110b0f665,

title = "Resonance Raman Study of Tetrakis(p-sulfonatophenyl) porphyrin Diacid (H2+4TSPP) Molecular Aggregates",

abstract = "Polarized resonance Raman spectra of J-aggregated tetrakis(p-sulfonatophenyl) porphyrin diacid (H2+4TSPP) were reported. In addition, resonance Raman spectra of molecular state H2+4TSPP and the free base H2TSPP were also recorded for comparison. The observed Raman bands of the aggregates were assigned based on their isotopic shifts upon deuteration. The low-frequency bands at 81, 119 and 141 cm-1 were assigned to intermolecular lattice modes. The structure alteration of H2+4TSPP induced by the aggregation was evaluated by comparing the resonance Raman spectra of the aggregated H2+4TSPP with those of the molecular state H2+4TSPP. It was deduced that H2+4TSPP in the aggregates is arranged in a face-to-face manner.",

keywords = "Molecular aggregates, Porphyrins, Resonance raman",

author = "Chen, \{Dong Ming\} and Li, \{Xiao Yuan\} and Yu, \{Nai Teng\} and Zhang, \{Ying Hui\} and He, \{Tian Jing\} and Liu, \{Fan Zhen\}",

year = "1999",

month = jul,

day = "10",

language = "English",

volume = "20",

pages = "1101",

journal = "Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "7",

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TY - JOUR

T1 - Resonance Raman Study of Tetrakis(p-sulfonatophenyl) porphyrin Diacid (H2+4TSPP) Molecular Aggregates

AU - Chen, Dong Ming

AU - Li, Xiao Yuan

AU - Yu, Nai Teng

AU - Zhang, Ying Hui

AU - He, Tian Jing

AU - Liu, Fan Zhen

PY - 1999/7/10

Y1 - 1999/7/10

N2 - Polarized resonance Raman spectra of J-aggregated tetrakis(p-sulfonatophenyl) porphyrin diacid (H2+4TSPP) were reported. In addition, resonance Raman spectra of molecular state H2+4TSPP and the free base H2TSPP were also recorded for comparison. The observed Raman bands of the aggregates were assigned based on their isotopic shifts upon deuteration. The low-frequency bands at 81, 119 and 141 cm-1 were assigned to intermolecular lattice modes. The structure alteration of H2+4TSPP induced by the aggregation was evaluated by comparing the resonance Raman spectra of the aggregated H2+4TSPP with those of the molecular state H2+4TSPP. It was deduced that H2+4TSPP in the aggregates is arranged in a face-to-face manner.

AB - Polarized resonance Raman spectra of J-aggregated tetrakis(p-sulfonatophenyl) porphyrin diacid (H2+4TSPP) were reported. In addition, resonance Raman spectra of molecular state H2+4TSPP and the free base H2TSPP were also recorded for comparison. The observed Raman bands of the aggregates were assigned based on their isotopic shifts upon deuteration. The low-frequency bands at 81, 119 and 141 cm-1 were assigned to intermolecular lattice modes. The structure alteration of H2+4TSPP induced by the aggregation was evaluated by comparing the resonance Raman spectra of the aggregated H2+4TSPP with those of the molecular state H2+4TSPP. It was deduced that H2+4TSPP in the aggregates is arranged in a face-to-face manner.

KW - Molecular aggregates

KW - Porphyrins

KW - Resonance raman

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000081746300024

M3 - Journal Article

SN - 0251-0790

VL - 20

SP - 1101

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 7

ER -

Resonance Raman Study of Tetrakis(p-sulfonatophenyl) porphyrin Diacid (H²⁺₄TSPP) Molecular Aggregates

Abstract

Keywords

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