Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride

Long Chen; Teng Zhou; Lifang Chen; Yinmei Ye; Zhiwen Qi; Hannsjörg Freund; Kai Sundmacher

Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride

Long Chen, Teng Zhou, Lifang Chen, Yinmei Ye, Zhiwen Qi^*, Hannsjörg Freund, Kai Sundmacher

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

50 Citations (Scopus)

Abstract

Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100% conversion of cyclohexanol with 100% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO₃ as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory.

Original language	English
Pages (from-to)	9354-9356
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	33
Publication status	Published - 7 Sept 2011
Externally published	Yes

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https://hdl.handle.net/1783.1/122051

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title = "Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride",

abstract = "Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100\% conversion of cyclohexanol with 100\% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO3 as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory.",

author = "Long Chen and Teng Zhou and Lifang Chen and Yinmei Ye and Zhiwen Qi and Hannsj{\"o}rg Freund and Kai Sundmacher",

year = "2011",

month = sep,

day = "7",

language = "English",

volume = "47",

pages = "9354--9356",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "33",

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TY - JOUR

T1 - Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride

AU - Chen, Long

AU - Zhou, Teng

AU - Chen, Lifang

AU - Ye, Yinmei

AU - Qi, Zhiwen

AU - Freund, Hannsjörg

AU - Sundmacher, Kai

PY - 2011/9/7

Y1 - 2011/9/7

N2 - Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100% conversion of cyclohexanol with 100% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO3 as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory.

AB - Ionic liquid (IL) 1-octyl-3-methylimidazolium chloride was found to effectively intensify cyclohexanol oxidation and resulted in 100% conversion of cyclohexanol with 100% selectivity to cyclohexanone using hydrogen peroxide as an oxidant and WO3 as a catalyst. The effect of the IL as a solvent is discussed with the support of COSMO-RS theory.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000293648200018

UR - https://openalex.org/W2112382550

M3 - Journal Article

SN - 1359-7345

VL - 47

SP - 9354

EP - 9356

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid 1-octyl-3-methylimidazolium chloride

Abstract

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