Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS

L. Li; C. M. Chan; L. T. Weng; M. L. Xiang; M. Jiang

Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS

L. Li^*
, C. M. Chan
, L. T. Weng
, M. L. Xiang
, M. Jiang

^*Corresponding author for this work

Division of Environment and Sustainability

Research output: Contribution to journal › Conference article published in journal › peer-review

2 Citations (Scopus)

Abstract

The STVPy-72 copolymer is shown to form a polymer complex with STVPh-50 and PVPh, and to form a partial miscible blend with STVPh-22. Hydrogen bonding can induce 0.6 shift in the N is binding energy for the pyridyl units and a 0.5 eV shift in the O is binding energy for the phenol units in the complex of STVPh-50/STVPy-72. A characterization of the surface morphology of the STVPh-22/STVPy-72 blend is conducted using ToF-SIMS imaging. It is shown that the STVPh-22 and the STVPy-72 are immiscible and that two phases are present on the surface. STVPh-22 particles from a discrete phase and a mixture of STVPh-22/STVPy-72 which forms a continuous matrix.

Original language	English
Pages (from-to)	1173-1174
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	39
Issue number	2
Publication status	Published - Aug 1998
Event	Proceedings of the 1997 Boston Meeting - Boston, MA, USA Duration: 23 Aug 1998 → 27 Aug 1998

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@article{dd8a05035be24627b3f8e8bc52f2ed36,

title = "Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS",

abstract = "The STVPy-72 copolymer is shown to form a polymer complex with STVPh-50 and PVPh, and to form a partial miscible blend with STVPh-22. Hydrogen bonding can induce 0.6 shift in the N is binding energy for the pyridyl units and a 0.5 eV shift in the O is binding energy for the phenol units in the complex of STVPh-50/STVPy-72. A characterization of the surface morphology of the STVPh-22/STVPy-72 blend is conducted using ToF-SIMS imaging. It is shown that the STVPh-22 and the STVPy-72 are immiscible and that two phases are present on the surface. STVPh-22 particles from a discrete phase and a mixture of STVPh-22/STVPy-72 which forms a continuous matrix.",

author = "L. Li and Chan, \{C. M.\} and Weng, \{L. T.\} and Xiang, \{M. L.\} and M. Jiang",

year = "1998",

month = aug,

language = "English",

volume = "39",

pages = "1173--1174",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "2",

note = "Proceedings of the 1997 Boston Meeting ; Conference date: 23-08-1998 Through 27-08-1998",

}

Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS. / Li, L.; Chan, C. M.; Weng, L. T. et al.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 39, No. 2, 08.1998, p. 1173-1174.

Research output: Contribution to journal › Conference article published in journal › peer-review

TY - JOUR

T1 - Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS

AU - Li, L.

AU - Chan, C. M.

AU - Weng, L. T.

AU - Xiang, M. L.

AU - Jiang, M.

PY - 1998/8

Y1 - 1998/8

N2 - The STVPy-72 copolymer is shown to form a polymer complex with STVPh-50 and PVPh, and to form a partial miscible blend with STVPh-22. Hydrogen bonding can induce 0.6 shift in the N is binding energy for the pyridyl units and a 0.5 eV shift in the O is binding energy for the phenol units in the complex of STVPh-50/STVPy-72. A characterization of the surface morphology of the STVPh-22/STVPy-72 blend is conducted using ToF-SIMS imaging. It is shown that the STVPh-22 and the STVPy-72 are immiscible and that two phases are present on the surface. STVPh-22 particles from a discrete phase and a mixture of STVPh-22/STVPy-72 which forms a continuous matrix.

AB - The STVPy-72 copolymer is shown to form a polymer complex with STVPh-50 and PVPh, and to form a partial miscible blend with STVPh-22. Hydrogen bonding can induce 0.6 shift in the N is binding energy for the pyridyl units and a 0.5 eV shift in the O is binding energy for the phenol units in the complex of STVPh-50/STVPy-72. A characterization of the surface morphology of the STVPh-22/STVPy-72 blend is conducted using ToF-SIMS imaging. It is shown that the STVPh-22 and the STVPy-72 are immiscible and that two phases are present on the surface. STVPh-22 particles from a discrete phase and a mixture of STVPh-22/STVPy-72 which forms a continuous matrix.

UR - https://www.scopus.com/pages/publications/0032139128

M3 - Conference article published in journal

AN - SCOPUS:0032139128

SN - 0032-3934

VL - 39

SP - 1173

EP - 1174

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Proceedings of the 1997 Boston Meeting

Y2 - 23 August 1998 through 27 August 1998

ER -

Surface study of poly(styrene-co-4-vinylphenol) and poly(styrene-co-4-vinylpyridine) blends by XPS and TOF-SIMS

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