Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

Haiping Xia; Ting Bin Wen; Quan Yuan Hu; Xin Wang; Xingguo Chen; Lai Yung Shek; Ian D. Williams; Kam Sing Wong; George K.L. Wong; Guochen Jia

doi:10.1021/om0496939

Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

Haiping Xia, Ting Bin Wen, Quan Yuan Hu, Xin Wang, Xingguo Chen, Lai Yung Shek, Ian D. Williams, Kam Sing Wong^*, George K.L. Wong, Guochen Jia

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

57 Citations (Scopus)

Abstract

Treatment of RuHCl(CO)(PPh₃)₃ with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh ₃)₂RuCH=CH]₃C₆H₃, which reacts with PMe₃ to give 1,3,5-[Cl-(CO)(PMe₃) ₃RuCH=CH]₃C₆H₃. 1,3,5-[Cl(CO) (PPh₃)₂RuCH=CH]₃C₆H₃ also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh₃)₂RuCH=CH]₃C ₆H₃ (L = Py, PhPy). Reactions of OsHCl(CO)(PPh ₃)₃ with ArC≡CH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh₃) ₃. Reaction of OsHCl(CO)-(PPh₃)₃ with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HC≡C-3,5-[Cl(CO) -(PPh₃)₃OsCH=CH]₂C₆H₃, which reacts with PMe₃ to give 1-HC≡C-3,5-[OsCl(CO)(PPh ₃)₂-(PMe₃)OsCH=CH]₂C ₆H₃. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

Original language	English
Pages (from-to)	562-569
Number of pages	8
Journal	Organometallics
Volume	24
Issue number	4
DOIs	https://doi.org/10.1021/om0496939
Publication status	Published - 14 Feb 2005

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@article{4a64c25102ec45d2aeaef0a8eca928b0,

title = "Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages",

abstract = "Treatment of RuHCl(CO)(PPh3)3 with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh 3)2RuCH=CH]3C6H3, which reacts with PMe3 to give 1,3,5-[Cl-(CO)(PMe3) 3RuCH=CH]3C6H3. 1,3,5-[Cl(CO) (PPh3)2RuCH=CH]3C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)2RuCH=CH]3C 6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh 3)3 with ArC≡CH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3) 3. Reaction of OsHCl(CO)-(PPh3)3 with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HC≡C-3,5-[Cl(CO) -(PPh3)3OsCH=CH]2C6H3, which reacts with PMe3 to give 1-HC≡C-3,5-[OsCl(CO)(PPh 3)2-(PMe3)OsCH=CH]2C 6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.",

author = "Haiping Xia and Wen, \{Ting Bin\} and Hu, \{Quan Yuan\} and Xin Wang and Xingguo Chen and Shek, \{Lai Yung\} and Williams, \{Ian D.\} and Wong, \{Kam Sing\} and Wong, \{George K.L.\} and Guochen Jia",

year = "2005",

month = feb,

day = "14",

doi = "10.1021/om0496939",

language = "English",

volume = "24",

pages = "562--569",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

AU - Xia, Haiping

AU - Wen, Ting Bin

AU - Hu, Quan Yuan

AU - Wang, Xin

AU - Chen, Xingguo

AU - Shek, Lai Yung

AU - Williams, Ian D.

AU - Wong, Kam Sing

AU - Wong, George K.L.

AU - Jia, Guochen

PY - 2005/2/14

Y1 - 2005/2/14

N2 - Treatment of RuHCl(CO)(PPh3)3 with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh 3)2RuCH=CH]3C6H3, which reacts with PMe3 to give 1,3,5-[Cl-(CO)(PMe3) 3RuCH=CH]3C6H3. 1,3,5-[Cl(CO) (PPh3)2RuCH=CH]3C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)2RuCH=CH]3C 6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh 3)3 with ArC≡CH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3) 3. Reaction of OsHCl(CO)-(PPh3)3 with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HC≡C-3,5-[Cl(CO) -(PPh3)3OsCH=CH]2C6H3, which reacts with PMe3 to give 1-HC≡C-3,5-[OsCl(CO)(PPh 3)2-(PMe3)OsCH=CH]2C 6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

AB - Treatment of RuHCl(CO)(PPh3)3 with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh 3)2RuCH=CH]3C6H3, which reacts with PMe3 to give 1,3,5-[Cl-(CO)(PMe3) 3RuCH=CH]3C6H3. 1,3,5-[Cl(CO) (PPh3)2RuCH=CH]3C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)2RuCH=CH]3C 6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh 3)3 with ArC≡CH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3) 3. Reaction of OsHCl(CO)-(PPh3)3 with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HC≡C-3,5-[Cl(CO) -(PPh3)3OsCH=CH]2C6H3, which reacts with PMe3 to give 1-HC≡C-3,5-[OsCl(CO)(PPh 3)2-(PMe3)OsCH=CH]2C 6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000226924800016

UR - https://openalex.org/W1971016000

UR - https://www.scopus.com/pages/publications/20044390736

U2 - 10.1021/om0496939

DO - 10.1021/om0496939

M3 - Journal Article

SN - 0276-7333

VL - 24

SP - 562

EP - 569

JO - Organometallics

JF - Organometallics

IS - 4

ER -

Synthesis and characterization of trimetallic ruthenium and bimetallic osmium complexes with metal-vinyl linkages

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