Synthesis and light-emitting properties of poly(carbazolylacetylenes)

Priscilla Pui Sze Lee; Yanhou Geng; Hoi Sing Kwok; Ben Zhong Tang

doi:10.1016/S0040-6090(99)01029-9

Synthesis and light-emitting properties of poly(carbazolylacetylenes)

Priscilla Pui Sze Lee, Yanhou Geng, Hoi Sing Kwok, Ben Zhong Tang

Research output: Contribution to journal › Conference article published in journal › peer-review

40 Citations (Scopus)

Abstract

A group of new carbazole-containing polyacetylenes, poly[n-(9-carbazolyl)-1-alkynes] [m = n-2; m = 3 (P2a), 9 (P2b)], poly[5-(3,6-dibromo-9-carbazolyl)-1-pentyne] (P3a), and poly[n-(9-carbazolyl)-1-chloro-1-alkynes] [m = n-2; m = 3 (P4a), m = 9 (P4b)], have been synthesized using WCl₆-Ph₄Sn and MoCl₅-Ph₄Sn as catalysts. High molecular weight (up to 500 000) polymers have been obtained in high yields (up to 80%). The molecular structures of the polymers are characterized by spectroscopic methods. All the monomers except (P2a) are highly luminescent. The polymer with a long spacer length (P2b) emits intense deep-blue light when excited at 295 nm.

Original language	English
Pages (from-to)	149-151
Number of pages	3
Journal	Thin Solid Films
Volume	363
Issue number	1
DOIs	https://doi.org/10.1016/S0040-6090(99)01029-9
Publication status	Published - 1 Mar 2000
Event	The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices - Hong Kong, Hong Kong Duration: 8 Jun 1999 → 11 Jun 1999

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@article{763db565dbd445ab9d2bd2f4ed0614a0,

title = "Synthesis and light-emitting properties of poly(carbazolylacetylenes)",

abstract = "A group of new carbazole-containing polyacetylenes, poly[n-(9-carbazolyl)-1-alkynes] [m = n-2; m = 3 (P2a), 9 (P2b)], poly[5-(3,6-dibromo-9-carbazolyl)-1-pentyne] (P3a), and poly[n-(9-carbazolyl)-1-chloro-1-alkynes] [m = n-2; m = 3 (P4a), m = 9 (P4b)], have been synthesized using WCl6-Ph4Sn and MoCl5-Ph4Sn as catalysts. High molecular weight (up to 500 000) polymers have been obtained in high yields (up to 80\%). The molecular structures of the polymers are characterized by spectroscopic methods. All the monomers except (P2a) are highly luminescent. The polymer with a long spacer length (P2b) emits intense deep-blue light when excited at 295 nm.",

author = "Lee, \{Priscilla Pui Sze\} and Yanhou Geng and Kwok, \{Hoi Sing\} and Tang, \{Ben Zhong\}",

year = "2000",

month = mar,

day = "1",

doi = "10.1016/S0040-6090(99)01029-9",

language = "English",

volume = "363",

pages = "149--151",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier B.V.",

number = "1",

note = "The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices ; Conference date: 08-06-1999 Through 11-06-1999",

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TY - JOUR

T1 - Synthesis and light-emitting properties of poly(carbazolylacetylenes)

AU - Lee, Priscilla Pui Sze

AU - Geng, Yanhou

AU - Kwok, Hoi Sing

AU - Tang, Ben Zhong

PY - 2000/3/1

Y1 - 2000/3/1

N2 - A group of new carbazole-containing polyacetylenes, poly[n-(9-carbazolyl)-1-alkynes] [m = n-2; m = 3 (P2a), 9 (P2b)], poly[5-(3,6-dibromo-9-carbazolyl)-1-pentyne] (P3a), and poly[n-(9-carbazolyl)-1-chloro-1-alkynes] [m = n-2; m = 3 (P4a), m = 9 (P4b)], have been synthesized using WCl6-Ph4Sn and MoCl5-Ph4Sn as catalysts. High molecular weight (up to 500 000) polymers have been obtained in high yields (up to 80%). The molecular structures of the polymers are characterized by spectroscopic methods. All the monomers except (P2a) are highly luminescent. The polymer with a long spacer length (P2b) emits intense deep-blue light when excited at 295 nm.

AB - A group of new carbazole-containing polyacetylenes, poly[n-(9-carbazolyl)-1-alkynes] [m = n-2; m = 3 (P2a), 9 (P2b)], poly[5-(3,6-dibromo-9-carbazolyl)-1-pentyne] (P3a), and poly[n-(9-carbazolyl)-1-chloro-1-alkynes] [m = n-2; m = 3 (P4a), m = 9 (P4b)], have been synthesized using WCl6-Ph4Sn and MoCl5-Ph4Sn as catalysts. High molecular weight (up to 500 000) polymers have been obtained in high yields (up to 80%). The molecular structures of the polymers are characterized by spectroscopic methods. All the monomers except (P2a) are highly luminescent. The polymer with a long spacer length (P2b) emits intense deep-blue light when excited at 295 nm.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000085664000038

UR - https://openalex.org/W2095476917

UR - https://www.scopus.com/pages/publications/0013164385

U2 - 10.1016/S0040-6090(99)01029-9

DO - 10.1016/S0040-6090(99)01029-9

M3 - Conference article published in journal

SN - 0040-6090

VL - 363

SP - 149

EP - 151

JO - Thin Solid Films

JF - Thin Solid Films

IS - 1

T2 - The Asia-Pacific Symposium on Organic Electroluminescent Materials and Devices

Y2 - 8 June 1999 through 11 June 1999

ER -

Synthesis and light-emitting properties of poly(carbazolylacetylenes)

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