Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)2{(Ph2PCH2)2-C18H10}]BF4

D. Michael P. Mingos; Darren J. Sherman; Ian D. Williams

doi:10.1007/BF01023832

Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)₂{(Ph₂PCH₂)₂-C₁₈H₁₀}]BF₄

D. Michael P. Mingos^*, Darren J. Sherman, Ian D. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

6 Citations (Scopus)

Abstract

[RuCl(NO)₂(dppbp)]BF₄ (dppbp=(Ph₂PCH₂)_2-) has been synthesised from [RuCl(NO)₂(PPh₃)₂]BF₄ and dppbp and characterised in the solid state by a single crystal x-ray determination. The [RuCl(NO)₂(dppbp)]⁺ cation, has an approximately square-pyramidal co-ordination geometry with the dppbp ligand occupying trans-basal sites. The nitrosyl ligand in the apical site is partially bent [Ru-N-O=156.2(7)⁰] and the nitrosyl ligand in the basal side is essentially linear [Ru-N-O=172.5(6)⁰]. The¹Hn.m.r. spectrum of [RuCl(NO)₂(dppbp)]BF₄ in solution has provided some insight into the dynamics of the complex in solution.

Original language	English
Pages (from-to)	493-496
Number of pages	4
Journal	Transition Metal Chemistry
Volume	12
Issue number	6
DOIs	https://doi.org/10.1007/BF01023832
Publication status	Published - Dec 1987
Externally published	Yes

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Mingos, D. M. P., Sherman, D. J., & Williams, I. D. (1987). Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)₂{(Ph₂PCH₂)₂-C₁₈H₁₀}]BF₄. Transition Metal Chemistry, 12(6), 493-496. https://doi.org/10.1007/BF01023832

Mingos, D. Michael P. ; Sherman, Darren J. ; Williams, Ian D. / Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)₂{(Ph₂PCH₂)₂-C₁₈H₁₀}]BF₄. In: Transition Metal Chemistry. 1987 ; Vol. 12, No. 6. pp. 493-496.

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title = "Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)2\{(Ph2PCH2)2-C18H10\}]BF4",

abstract = "[RuCl(NO)2(dppbp)]BF4 (dppbp=(Ph2PCH2)2-) has been synthesised from [RuCl(NO)2(PPh3)2]BF4 and dppbp and characterised in the solid state by a single crystal x-ray determination. The [RuCl(NO)2(dppbp)]+ cation, has an approximately square-pyramidal co-ordination geometry with the dppbp ligand occupying trans-basal sites. The nitrosyl ligand in the apical site is partially bent [Ru-N-O=156.2(7)0] and the nitrosyl ligand in the basal side is essentially linear [Ru-N-O=172.5(6)0]. The1Hn.m.r. spectrum of [RuCl(NO)2(dppbp)]BF4 in solution has provided some insight into the dynamics of the complex in solution.",

author = "Mingos, \{D. Michael P.\} and Sherman, \{Darren J.\} and Williams, \{Ian D.\}",

year = "1987",

month = dec,

doi = "10.1007/BF01023832",

language = "English",

volume = "12",

pages = "493--496",

journal = "Transition Metal Chemistry",

issn = "0304-4285",

number = "6",

}

Mingos, DMP, Sherman, DJ & Williams, ID 1987, 'Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)₂{(Ph₂PCH₂)₂-C₁₈H₁₀}]BF₄', Transition Metal Chemistry, vol. 12, no. 6, pp. 493-496. https://doi.org/10.1007/BF01023832

Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)₂{(Ph₂PCH₂)₂-C₁₈H₁₀}]BF₄. / Mingos, D. Michael P.; Sherman, Darren J.; Williams, Ian D.
In: Transition Metal Chemistry, Vol. 12, No. 6, 12.1987, p. 493-496.

Research output: Contribution to journal › Journal Article › peer-review

TY - JOUR

T1 - Synthesis and structural characterisation of a ruthenium dinitrosyl complex with a trans-chelating bidentate diphosphine (1,10-bis(diphenylphosphinomethyl) [a] benzophenanthrene) chlorodi(nitrosyl)ruthenium tetrafluoroborate, [RuCl(NO)2{(Ph2PCH2)2-C18H10}]BF4

AU - Mingos, D. Michael P.

AU - Sherman, Darren J.

AU - Williams, Ian D.

PY - 1987/12

Y1 - 1987/12

N2 - [RuCl(NO)2(dppbp)]BF4 (dppbp=(Ph2PCH2)2-) has been synthesised from [RuCl(NO)2(PPh3)2]BF4 and dppbp and characterised in the solid state by a single crystal x-ray determination. The [RuCl(NO)2(dppbp)]+ cation, has an approximately square-pyramidal co-ordination geometry with the dppbp ligand occupying trans-basal sites. The nitrosyl ligand in the apical site is partially bent [Ru-N-O=156.2(7)0] and the nitrosyl ligand in the basal side is essentially linear [Ru-N-O=172.5(6)0]. The1Hn.m.r. spectrum of [RuCl(NO)2(dppbp)]BF4 in solution has provided some insight into the dynamics of the complex in solution.

AB - [RuCl(NO)2(dppbp)]BF4 (dppbp=(Ph2PCH2)2-) has been synthesised from [RuCl(NO)2(PPh3)2]BF4 and dppbp and characterised in the solid state by a single crystal x-ray determination. The [RuCl(NO)2(dppbp)]+ cation, has an approximately square-pyramidal co-ordination geometry with the dppbp ligand occupying trans-basal sites. The nitrosyl ligand in the apical site is partially bent [Ru-N-O=156.2(7)0] and the nitrosyl ligand in the basal side is essentially linear [Ru-N-O=172.5(6)0]. The1Hn.m.r. spectrum of [RuCl(NO)2(dppbp)]BF4 in solution has provided some insight into the dynamics of the complex in solution.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:A1987P368400002

UR - https://openalex.org/W1973649355

UR - https://www.scopus.com/pages/publications/0011614108

U2 - 10.1007/BF01023832

DO - 10.1007/BF01023832

M3 - Journal Article

SN - 0304-4285

VL - 12

SP - 493

EP - 496

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 6

ER -