Synthesis of a Dy@C82 derivative bearing a single phosphorus substituent via a Zwitterion approach

Xiaofang Li, Louzhen Fan, Dongfang Liu, Herman H.Y. Sung, Ian D. Williams, Shihe Yang*, Kai Tan, Xin Lu

*Corresponding author for this work

Research output: Contribution to journalJournal Articlepeer-review

37 Citations (Scopus)

Abstract

A Dy@C82 derivative bearing a single phosphorus substituent has been obtained in 90% yield by the regio- and chemoselective zwitterion reaction of Dy@C82 with dimethyl acetylenedicarboxylate and triphenylphosphine. The structure of the product is confirmed by MS, UV-vis-NIR spectroscopy, and X-ray crystallography.

Original languageEnglish
Pages (from-to)10636-10637
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number35
DOIs
Publication statusPublished - 5 Sept 2007

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