Synthesis of poly(2,5-di-n-butoxy-p-phenylene vinylene) and its application in light-emitting diodes

Guojie Wang; Jingsong Huang; Min Li; Xinfang Chen; Shiyong Liu

doi:10.1002/pen.11291

Synthesis of poly(2,5-di-n-butoxy-p-phenylene vinylene) and its application in light-emitting diodes

Guojie Wang, Jingsong Huang, Min Li, Xinfang Chen, Shiyong Liu

Research output: Contribution to journal › Journal Article › peer-review

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Abstract

Poly(2,5-di-n-butoxy-p-phenylene vinylene) (DBPPV) was synthesized in a mixed solvent of xylene and tertbutyl alcohol via a dehydrochlorination route, using potassium tert-butoxide as the initiator. The polymer was soluble in organic solvents such as xylene, chloroform and THF. The polymer was characterized by elemental analysis, FTIR, ¹H NMR and UV-Visible spectroscopy. Single-layer and a double-layer light-emitting diodes (LEDs) were fabricated using the polymer as the active layer. The peaks of the photoluminescence (pl) and electroluminescence (el) spectra of the LEDs were at 580 nm and 577 nm, respectively. The turn-on voltage and the maximum luminescence of the single-layer LED were 6.4V, and 100 cd/m², while that of the double-layer LED were 4.3V, and 630 cd/m², respectively.

Original language	English
Pages (from-to)	1606-1610
Number of pages	5
Journal	Polymer Engineering and Science
Volume	40
Issue number	7
DOIs	https://doi.org/10.1002/pen.11291
Publication status	Published - 2000
Externally published	Yes

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title = "Synthesis of poly(2,5-di-n-butoxy-p-phenylene vinylene) and its application in light-emitting diodes",

abstract = "Poly(2,5-di-n-butoxy-p-phenylene vinylene) (DBPPV) was synthesized in a mixed solvent of xylene and tertbutyl alcohol via a dehydrochlorination route, using potassium tert-butoxide as the initiator. The polymer was soluble in organic solvents such as xylene, chloroform and THF. The polymer was characterized by elemental analysis, FTIR, 1H NMR and UV-Visible spectroscopy. Single-layer and a double-layer light-emitting diodes (LEDs) were fabricated using the polymer as the active layer. The peaks of the photoluminescence (pl) and electroluminescence (el) spectra of the LEDs were at 580 nm and 577 nm, respectively. The turn-on voltage and the maximum luminescence of the single-layer LED were 6.4V, and 100 cd/m2, while that of the double-layer LED were 4.3V, and 630 cd/m2, respectively.",

author = "Guojie Wang and Jingsong Huang and Min Li and Xinfang Chen and Shiyong Liu",

year = "2000",

doi = "10.1002/pen.11291",

language = "English",

volume = "40",

pages = "1606--1610",

journal = "Polymer Engineering and Science",

issn = "0032-3888",

publisher = "John Wiley and Sons Inc",

number = "7",

}

TY - JOUR

T1 - Synthesis of poly(2,5-di-n-butoxy-p-phenylene vinylene) and its application in light-emitting diodes

AU - Wang, Guojie

AU - Huang, Jingsong

AU - Li, Min

AU - Chen, Xinfang

AU - Liu, Shiyong

PY - 2000

Y1 - 2000

N2 - Poly(2,5-di-n-butoxy-p-phenylene vinylene) (DBPPV) was synthesized in a mixed solvent of xylene and tertbutyl alcohol via a dehydrochlorination route, using potassium tert-butoxide as the initiator. The polymer was soluble in organic solvents such as xylene, chloroform and THF. The polymer was characterized by elemental analysis, FTIR, 1H NMR and UV-Visible spectroscopy. Single-layer and a double-layer light-emitting diodes (LEDs) were fabricated using the polymer as the active layer. The peaks of the photoluminescence (pl) and electroluminescence (el) spectra of the LEDs were at 580 nm and 577 nm, respectively. The turn-on voltage and the maximum luminescence of the single-layer LED were 6.4V, and 100 cd/m2, while that of the double-layer LED were 4.3V, and 630 cd/m2, respectively.

AB - Poly(2,5-di-n-butoxy-p-phenylene vinylene) (DBPPV) was synthesized in a mixed solvent of xylene and tertbutyl alcohol via a dehydrochlorination route, using potassium tert-butoxide as the initiator. The polymer was soluble in organic solvents such as xylene, chloroform and THF. The polymer was characterized by elemental analysis, FTIR, 1H NMR and UV-Visible spectroscopy. Single-layer and a double-layer light-emitting diodes (LEDs) were fabricated using the polymer as the active layer. The peaks of the photoluminescence (pl) and electroluminescence (el) spectra of the LEDs were at 580 nm and 577 nm, respectively. The turn-on voltage and the maximum luminescence of the single-layer LED were 6.4V, and 100 cd/m2, while that of the double-layer LED were 4.3V, and 630 cd/m2, respectively.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000088459800013

U2 - 10.1002/pen.11291

DO - 10.1002/pen.11291

M3 - Journal Article

SN - 0032-3888

VL - 40

SP - 1606

EP - 1610

JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

IS - 7

ER -

Synthesis of poly(2,5-di-n-butoxy-p-phenylene vinylene) and its application in light-emitting diodes

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