Synthesis, Structure and Electrochemistry of [Ru2(S 2CNMe2)3(μ3-S 2CNMe2)2]2[Mo6O 19]·2CH3COCH3

Fang Hui Wu; Yang Li Liub; Duanb Taike; Lua Lude; Qian Feng Zhang; Wa Hung Leung

doi:10.1515/znb-2009-0704

Synthesis, Structure and Electrochemistry of [Ru₂(S ₂CNMe₂)₃(μ₃-S ₂CNMe₂)₂]₂[Mo₆O ₁₉]·2CH₃COCH₃

Fang Hui Wu^*
, Yang Li Liub
, Duanb Taike
, Lua Lude
, Qian Feng Zhang
, Wa Hung Leung

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

3 Citations (Scopus)

Abstract

Reaction ofMoO₂(S₂CNMe₂)₂ with RuCl₃·xH₂O in acetone at reflux afforded [Ru ₂(S₂CNMe₂)₃-(μ₃-S ₂CNMe₂)₂]₂[Mo6O₁₉] ·2CH₃COCH₃ (1·2CH₃COCH ₃) which was characterized by singlecrystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru₂(S₂CNMe₂) ₃(μ₃-S₂CNMe₂)₂]+ cation may be considered as a combination of [Ru(S₂CNMe ₂)₃] with a cis-[Ru(S₂CNMe₂) ₂]+ species, and the Lindqvist anion [Mo₆O ₁₉]₂-is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1·2CH₃COCH₃ are reported.

Original language	English
Pages (from-to)	800-804
Number of pages	5
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	64
Issue number	7
DOIs	https://doi.org/10.1515/znb-2009-0704
Publication status	Published - 2009

Keywords

Crystal structure
Dithiocarbamate
Electrochemistry
Hexamolybdate
Ruthenium
Synthesis

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@article{ff504f02a82b4197882e860d793a568d,

title = "Synthesis, Structure and Electrochemistry of [Ru2(S 2CNMe2)3(μ3-S 2CNMe2)2]2[Mo6O 19]·2CH3COCH3",

abstract = "Reaction ofMoO2(S2CNMe2)2 with RuCl3·xH2O in acetone at reflux afforded [Ru 2(S2CNMe2)3-(μ3-S 2CNMe2)2]2[Mo6O19] ·2CH3COCH3 (1·2CH3COCH 3) which was characterized by singlecrystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru2(S2CNMe2) 3(μ3-S2CNMe2)2]+ cation may be considered as a combination of [Ru(S2CNMe 2)3] with a cis-[Ru(S2CNMe2) 2]+ species, and the Lindqvist anion [Mo6O 19]2-is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1·2CH3COCH3 are reported.",

keywords = "Crystal structure, Dithiocarbamate, Electrochemistry, Hexamolybdate, Ruthenium, Synthesis",

author = "Wu, \{Fang Hui\} and Liub, \{Yang Li\} and Duanb Taike and Lua Lude and Zhang, \{Qian Feng\} and Leung, \{Wa Hung\}",

year = "2009",

doi = "10.1515/znb-2009-0704",

language = "English",

volume = "64",

pages = "800--804",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "7",

}

TY - JOUR

T1 - Synthesis, Structure and Electrochemistry of [Ru2(S 2CNMe2)3(μ3-S 2CNMe2)2]2[Mo6O 19]·2CH3COCH3

AU - Wu, Fang Hui

AU - Liub, Yang Li

AU - Taike, Duanb

AU - Lude, Lua

AU - Zhang, Qian Feng

AU - Leung, Wa Hung

PY - 2009

Y1 - 2009

N2 - Reaction ofMoO2(S2CNMe2)2 with RuCl3·xH2O in acetone at reflux afforded [Ru 2(S2CNMe2)3-(μ3-S 2CNMe2)2]2[Mo6O19] ·2CH3COCH3 (1·2CH3COCH 3) which was characterized by singlecrystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru2(S2CNMe2) 3(μ3-S2CNMe2)2]+ cation may be considered as a combination of [Ru(S2CNMe 2)3] with a cis-[Ru(S2CNMe2) 2]+ species, and the Lindqvist anion [Mo6O 19]2-is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1·2CH3COCH3 are reported.

AB - Reaction ofMoO2(S2CNMe2)2 with RuCl3·xH2O in acetone at reflux afforded [Ru 2(S2CNMe2)3-(μ3-S 2CNMe2)2]2[Mo6O19] ·2CH3COCH3 (1·2CH3COCH 3) which was characterized by singlecrystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru2(S2CNMe2) 3(μ3-S2CNMe2)2]+ cation may be considered as a combination of [Ru(S2CNMe 2)3] with a cis-[Ru(S2CNMe2) 2]+ species, and the Lindqvist anion [Mo6O 19]2-is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1·2CH3COCH3 are reported.

KW - Crystal structure

KW - Dithiocarbamate

KW - Electrochemistry

KW - Hexamolybdate

KW - Ruthenium

KW - Synthesis

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000268602900004

UR - https://openalex.org/W2075573996

U2 - 10.1515/znb-2009-0704

DO - 10.1515/znb-2009-0704

M3 - Journal Article

SN - 0932-0776

VL - 64

SP - 800

EP - 804

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7

ER -

Synthesis, Structure and Electrochemistry of [Ru₂(S ₂CNMe₂)₃(μ₃-S ₂CNMe₂)₂]₂[Mo₆O ₁₉]·2CH₃COCH₃

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