The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Malcolm R. Binns; Oi Lee Chai; Richard K. Haynes; Andrew A. Katsifis; Paul A. Schober; Simone C. Vonwiller

doi:10.1016/S0040-4039(00)98554-X

The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Malcolm R. Binns^*, Oi Lee Chai, Richard K. Haynes, Andrew A. Katsifis, Paul A. Schober, Simone C. Vonwiller

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

35 Citations (Scopus)

Abstract

A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

Original language	English
Pages (from-to)	1569-1572
Number of pages	4
Journal	Tetrahedron Letters
Volume	26
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(00)98554-X
Publication status	Published - 1985
Externally published	Yes

Access to Document

10.1016/S0040-4039(00)98554-X

Cite this

@article{8ef07971e9df4bc4aeef0408a85f84a3,

title = "The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.",

abstract = "A ten-membered cyclic {"}chair-chair{"} - or {"}trans-decalyl{"}-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.",

author = "Binns, \{Malcolm R.\} and Chai, \{Oi Lee\} and Haynes, \{Richard K.\} and Katsifis, \{Andrew A.\} and Schober, \{Paul A.\} and Vonwiller, \{Simone C.\}",

year = "1985",

doi = "10.1016/S0040-4039(00)98554-X",

language = "English",

volume = "26",

pages = "1569--1572",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "12",

}

TY - JOUR

T1 - The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

AU - Binns, Malcolm R.

AU - Chai, Oi Lee

AU - Haynes, Richard K.

AU - Katsifis, Andrew A.

AU - Schober, Paul A.

AU - Vonwiller, Simone C.

PY - 1985

Y1 - 1985

N2 - A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

AB - A ten-membered cyclic "chair-chair" - or "trans-decalyl"-like TS is proposed to account for the diastereospecific aprotic conjugate addition reactions of allylic carbanions bearing polar, charge-stabilizing groups.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:A1985ADT5800029

UR - https://www.scopus.com/pages/publications/0000251480

U2 - 10.1016/S0040-4039(00)98554-X

DO - 10.1016/S0040-4039(00)98554-X

M3 - Journal Article

SN - 0040-4039

VL - 26

SP - 1569

EP - 1572

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

The diastereospecific aprotic conjugate addition reactions of allylic anions-mechanistic aspects.

Abstract

Access to Document

Other files and links

Fingerprint

Cite this