Two-dimensional assembly of the type Cd10Te4 thiolate cluster with 4,4′-trimethylenedipyridine

Chao Xu; Yan Gong Han; Taike Duan; Qian Feng Zhang; Wa Hung Leung

doi:10.1016/j.inoche.2009.08.018

Two-dimensional assembly of the type Cd₁₀Te₄ thiolate cluster with 4,4′-trimethylenedipyridine

Chao Xu
, Yan Gong Han
, Taike Duan
, Qian Feng Zhang^*
, Wa Hung Leung

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal Article › peer-review

14 Citations (Scopus)

Abstract

Cadmium tellurium cluster molecule [Cd₁₀Te₄(SC₆H₄Me-p)₁₂] and bifunctioanal organic ligand 4,4′-trimethylenedipyridine (tmdp) are joined together through metal-ligand coordination bonds, forming a new inorganic-organic hybrid polymeric cluster {Cd₁₀Te₄(SC₆H₄Me-p)₁₂(tmdp)₂}_n (1) with a unique two-dimensional super-structure. The room temperature absorption and the diffuse reflectance UV-Vis spectra along with the photo-luminescence behavior were determined in the solid state. The thermal stability of the polymeric cluster was studied by thermal gravimetric analysis.

Original language	English
Pages (from-to)	1053-1056
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	12
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2009.08.018
Publication status	Published - Oct 2009

Keywords

4,4′-Trimethylenedipyridine
Cadmium
Cluster compound
Crystal structure
Solvothermal synthesis
Tellurium

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10.1016/j.inoche.2009.08.018

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title = "Two-dimensional assembly of the type Cd10Te4 thiolate cluster with 4,4′-trimethylenedipyridine",

abstract = "Cadmium tellurium cluster molecule [Cd10Te4(SC6H4Me-p)12] and bifunctioanal organic ligand 4,4′-trimethylenedipyridine (tmdp) are joined together through metal-ligand coordination bonds, forming a new inorganic-organic hybrid polymeric cluster \{Cd10Te4(SC6H4Me-p)12(tmdp)2\}n (1) with a unique two-dimensional super-structure. The room temperature absorption and the diffuse reflectance UV-Vis spectra along with the photo-luminescence behavior were determined in the solid state. The thermal stability of the polymeric cluster was studied by thermal gravimetric analysis.",

keywords = "4,4′-Trimethylenedipyridine, Cadmium, Cluster compound, Crystal structure, Solvothermal synthesis, Tellurium",

author = "Chao Xu and Han, \{Yan Gong\} and Taike Duan and Zhang, \{Qian Feng\} and Leung, \{Wa Hung\}",

year = "2009",

month = oct,

doi = "10.1016/j.inoche.2009.08.018",

language = "English",

volume = "12",

pages = "1053--1056",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "10",

}

TY - JOUR

T1 - Two-dimensional assembly of the type Cd10Te4 thiolate cluster with 4,4′-trimethylenedipyridine

AU - Xu, Chao

AU - Han, Yan Gong

AU - Duan, Taike

AU - Zhang, Qian Feng

AU - Leung, Wa Hung

PY - 2009/10

Y1 - 2009/10

N2 - Cadmium tellurium cluster molecule [Cd10Te4(SC6H4Me-p)12] and bifunctioanal organic ligand 4,4′-trimethylenedipyridine (tmdp) are joined together through metal-ligand coordination bonds, forming a new inorganic-organic hybrid polymeric cluster {Cd10Te4(SC6H4Me-p)12(tmdp)2}n (1) with a unique two-dimensional super-structure. The room temperature absorption and the diffuse reflectance UV-Vis spectra along with the photo-luminescence behavior were determined in the solid state. The thermal stability of the polymeric cluster was studied by thermal gravimetric analysis.

AB - Cadmium tellurium cluster molecule [Cd10Te4(SC6H4Me-p)12] and bifunctioanal organic ligand 4,4′-trimethylenedipyridine (tmdp) are joined together through metal-ligand coordination bonds, forming a new inorganic-organic hybrid polymeric cluster {Cd10Te4(SC6H4Me-p)12(tmdp)2}n (1) with a unique two-dimensional super-structure. The room temperature absorption and the diffuse reflectance UV-Vis spectra along with the photo-luminescence behavior were determined in the solid state. The thermal stability of the polymeric cluster was studied by thermal gravimetric analysis.

KW - 4,4′-Trimethylenedipyridine

KW - Cadmium

KW - Cluster compound

KW - Crystal structure

KW - Solvothermal synthesis

KW - Tellurium

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000271356300031

UR - https://openalex.org/W1990249208

U2 - 10.1016/j.inoche.2009.08.018

DO - 10.1016/j.inoche.2009.08.018

M3 - Journal Article

SN - 1387-7003

VL - 12

SP - 1053

EP - 1056

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Two-dimensional assembly of the type Cd₁₀Te₄ thiolate cluster with 4,4′-trimethylenedipyridine

Abstract

Keywords

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