Abstract
Ultrathin chromium oxide films were prepared on a W(100) surface under ultrahigh-vacuum conditions and investigated in situ by X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy, and low-energy electron diffraction. The results show that, at Cr coverage of less than 1 monolayer, CrO2 is formed by oxidizing pre-deposited Cr at 300-320 K in ∼10-7 mbar oxygen. However, an increase of temperature causes formation of Cr2O3. At Cr coverage above 1 monolayer, only Cr2O3 is detected.
| Original language | English |
|---|---|
| Pages (from-to) | 20968-20972 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry B |
| Volume | 109 |
| Issue number | 44 |
| DOIs | |
| Publication status | Published - 10 Nov 2005 |
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