Vinyl complexes of diruthenium(IV) thiolates

Rufei Ye; Ai Quan Jia; Qing Maa; Qun Chen; Wa Hung Leung; Qian Feng Zhang

doi:10.1016/j.jorganchem.2013.05.017

Vinyl complexes of diruthenium(IV) thiolates

Rufei Ye
, Ai Quan Jia
, Qing Maa
, Qun Chen
, Wa Hung Leung
, Qian Feng Zhang^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Short survey › peer-review

4 Citations (Scopus)

Abstract

Treatment of [Et₄N][RuCl₄(MeCN)₂] with 2,4,6-trimethylthiophenol (HSMes) in the presence of NaOMe afforded the trigonalebipyramidal ruthenium(IV) complex [Ru(SMes)₄(MeCN)] (1), which reacted with propargylic alcohols HC=CR2OH (R = Me, Et) at ambient temperature to give the novel vinyl complexes of diruthenium(IV) thiolates [(μ-SMes)Ru{η¹-O,η¹-C-OCR₂CH]C(SMes) }(SMes)]₂ (R = Me 2, Et 3). The crystal structures of 2 and 3 have been determined. The Ru-Cα bond distances are 2.011(3) and 2.023(5) -A for 2 and 3, respectively.

Original language	English
Pages (from-to)	20-23
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	741-742
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2013.05.017
Publication status	Published - 2013

Keywords

Crystal structure
Ruthenium(IV)
Synthesis
Thiolate
Vinyl complex

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10.1016/j.jorganchem.2013.05.017

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@article{59892e2e54aa4330b9a201e341a46e3f,

title = "Vinyl complexes of diruthenium(IV) thiolates",

abstract = "Treatment of [Et4N][RuCl4(MeCN)2] with 2,4,6-trimethylthiophenol (HSMes) in the presence of NaOMe afforded the trigonalebipyramidal ruthenium(IV) complex [Ru(SMes)4(MeCN)] (1), which reacted with propargylic alcohols HC=CR2OH (R = Me, Et) at ambient temperature to give the novel vinyl complexes of diruthenium(IV) thiolates [(μ-SMes)Ru\{η1-O,η1-C-OCR2CH]C(SMes) \}(SMes)]2 (R = Me 2, Et 3). The crystal structures of 2 and 3 have been determined. The Ru-Cα bond distances are 2.011(3) and 2.023(5) -A for 2 and 3, respectively.",

keywords = "Crystal structure, Ruthenium(IV), Synthesis, Thiolate, Vinyl complex",

author = "Rufei Ye and Jia, \{Ai Quan\} and Qing Maa and Qun Chen and Leung, \{Wa Hung\} and Zhang, \{Qian Feng\}",

year = "2013",

doi = "10.1016/j.jorganchem.2013.05.017",

language = "English",

volume = "741-742",

pages = "20--23",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Vinyl complexes of diruthenium(IV) thiolates

AU - Ye, Rufei

AU - Jia, Ai Quan

AU - Maa, Qing

AU - Chen, Qun

AU - Leung, Wa Hung

AU - Zhang, Qian Feng

PY - 2013

Y1 - 2013

N2 - Treatment of [Et4N][RuCl4(MeCN)2] with 2,4,6-trimethylthiophenol (HSMes) in the presence of NaOMe afforded the trigonalebipyramidal ruthenium(IV) complex [Ru(SMes)4(MeCN)] (1), which reacted with propargylic alcohols HC=CR2OH (R = Me, Et) at ambient temperature to give the novel vinyl complexes of diruthenium(IV) thiolates [(μ-SMes)Ru{η1-O,η1-C-OCR2CH]C(SMes) }(SMes)]2 (R = Me 2, Et 3). The crystal structures of 2 and 3 have been determined. The Ru-Cα bond distances are 2.011(3) and 2.023(5) -A for 2 and 3, respectively.

AB - Treatment of [Et4N][RuCl4(MeCN)2] with 2,4,6-trimethylthiophenol (HSMes) in the presence of NaOMe afforded the trigonalebipyramidal ruthenium(IV) complex [Ru(SMes)4(MeCN)] (1), which reacted with propargylic alcohols HC=CR2OH (R = Me, Et) at ambient temperature to give the novel vinyl complexes of diruthenium(IV) thiolates [(μ-SMes)Ru{η1-O,η1-C-OCR2CH]C(SMes) }(SMes)]2 (R = Me 2, Et 3). The crystal structures of 2 and 3 have been determined. The Ru-Cα bond distances are 2.011(3) and 2.023(5) -A for 2 and 3, respectively.

KW - Crystal structure

KW - Ruthenium(IV)

KW - Synthesis

KW - Thiolate

KW - Vinyl complex

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:000322932700004

UR - https://openalex.org/W1971942888

U2 - 10.1016/j.jorganchem.2013.05.017

DO - 10.1016/j.jorganchem.2013.05.017

M3 - Short survey

SN - 0022-328X

VL - 741-742

SP - 20

EP - 23

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Vinyl complexes of diruthenium(IV) thiolates

Abstract

Keywords

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