Experimental and computational studies of the superconducting phase transition of quasi 1D superconductors

Abstract

In this PhD project, the feasibility of establishing a state with vanishing resistance in quasi-1D superconductors are studied. In the first stage, extrinsic quasi-1D superconductors based on composite materials made by metallic nanowire arrays embedded in mesoporous silica substrates, such as Pb-SBA-15 and NbN-SBA-15 (fabricated by a Chemical Vapor Deposition technique) are investigated. Two impressive outcomes in Pb-SBA-15 are found, including an enormous enhancement of the upper critical field from 0.08T to 14T and an increase of the superconducting transition temperature onset s from 7.2 to 11K. The second stage is to apply Monte Carlo simulations to model the quasi-1D superconductor, considering its penetration depth, coherence length, defects, electron mean free path, tunneling barrier and insulating width between the nanowires. The Monte Carlo results provide a clear picture to approach to stage 3, which represents a study of the intrinsic quasi-1D superconductor Sc₃CoC₄, which contains parallel arrays of 1D superconducting CoC₄ ribbons with weak transverse Josephson or Proximity interaction, embedded in a Sc matrix. According to our previous work, a BKT transition in the lateral plane is believed to be the physics behind the vanishing resistance of quasi-1D superconductors, because it activates a dimensional crossover from a 1D fluctuating superconductivity at high temperature to a 3D bulk phase coherent state in the entire material at low temperatures. Moreover, we decided to study thin 1D Sn nanowires without substrate, which display very similar superconducting properties to Pb-SBA-15 with a strong critical field and T_c enhancement. Finally, a preliminary research on a novel quasi-2D superconductor formed by parallel 2D mercury sheets that are separated by organic molecules is presented. The latter material may represent a model system to study the effect of a layered structure, which is believed to be an effective ingredient to design high temperature superconductors.

Date of Award	2015
Original language	English
Awarding Institution	The Hong Kong University of Science and Technology